<1S-(1α,2α,3α,4α)>-2-<<3-(hydroxymethyl)-7-oxabicyclo<2.2.1>hept-2-yl>methyl>benzoic acid

Base Information

Chemical Name:<1S-(1α,2α,3α,4α)>-2-<<3-(hydroxymethyl)-7-oxabicyclo<2.2.1>hept-2-yl>methyl>benzoic acid
CAS No.:1026078-60-3
Molecular Formula:C₁₅H₁₈O₄
Molecular Weight:262.306
Hs Code.:

Synonyms:<1S-(1α,2α,3α,4α)>-2-<<3-(hydroxymethyl)-7-oxabicyclo<2.2.1>hept-2-yl>methyl>benzoic acid

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Chemical Property of <1S-(1α,2α,3α,4α)>-2-<<3-(hydroxymethyl)-7-oxabicyclo<2.2.1>hept-2-yl>methyl>benzoic acid

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Technology Process of <1S-(1α,2α,3α,4α)>-2-<<3-(hydroxymethyl)-7-oxabicyclo<2.2.1>hept-2-yl>methyl>benzoic acid

There total 4 articles about <1S-(1α,2α,3α,4α)>-2-<<3-(hydroxymethyl)-7-oxabicyclo<2.2.1>hept-2-yl>methyl>benzoic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 3-((1S,2R,3R,4R)-3-Hydroxymethyl-7-oxa-bicyclo[2.2.1]hept-2-yl)-3H-isobenzofuran-1-one

: 1026078-60-3
<1S-(1α,2α,3α,4α)>-2-<<3-(hydroxymethyl)-7-oxabicyclo<2.2.1>hept-2-yl>methyl>benzoic acid

Guidance literature:: With hydrogen; palladium hydroxide - carbon; In acetic acid; for 96h; under 760 Torr; Ambient temperature;
DOI:10.1021/jm00062a013

Reference yield:

: 19312-06-2
4,5-dihydro-4,4-dimethyl-2-phenoxazole

: 1026078-60-3
<1S-(1α,2α,3α,4α)>-2-<<3-(hydroxymethyl)-7-oxabicyclo<2.2.1>hept-2-yl>methyl>benzoic acid

Guidance literature:: Multi-step reaction with 3 steps

1: 1.) n-BuLi / 1.) THF, hexane, -45 deg C, 3.5 h, 2.) THF, hexane, a) -45 deg C, 1 h, b) 25 deg C, 15 h

2: 5 percent aq. oxalic acid / 75 h / Ambient temperature

3: H₂ / 20percent Pd(OH)2-C / acetic acid / 96 h / 760 Torr / Ambient temperature

With n-butyllithium; hydrogen; oxalic acid; palladium hydroxide - carbon; In acetic acid;
DOI:10.1021/jm00062a013

Reference yield:

: 404575-34-4
7-oxabicyclo<2.2.1>heptane tetrahydrofuranol

: 1026078-60-3
<1S-(1α,2α,3α,4α)>-2-<<3-(hydroxymethyl)-7-oxabicyclo<2.2.1>hept-2-yl>methyl>benzoic acid

Guidance literature:: Multi-step reaction with 3 steps

1: 1.) n-BuLi / 1.) THF, hexane, -45 deg C, 3.5 h, 2.) THF, hexane, a) -45 deg C, 1 h, b) 25 deg C, 15 h

2: 5 percent aq. oxalic acid / 75 h / Ambient temperature

3: H₂ / 20percent Pd(OH)2-C / acetic acid / 96 h / 760 Torr / Ambient temperature

With n-butyllithium; hydrogen; oxalic acid; palladium hydroxide - carbon; In acetic acid;
DOI:10.1021/jm00062a013