tert-Butyl-dimethyl-(6-phenoxy-6H-5-oxa-11-thia-benzo[a]fluoren-9-yloxy)-silane

Base Information

Chemical Name:tert-Butyl-dimethyl-(6-phenoxy-6H-5-oxa-11-thia-benzo[a]fluoren-9-yloxy)-silane
CAS No.:188824-44-4
Molecular Formula:C₂₇H₂₈O₃SSi
Molecular Weight:460.669
Hs Code.:

Synonyms:tert-Butyl-dimethyl-(6-phenoxy-6H-5-oxa-11-thia-benzo[a]fluoren-9-yloxy)-silane

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of tert-Butyl-dimethyl-(6-phenoxy-6H-5-oxa-11-thia-benzo[a]fluoren-9-yloxy)-silane

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Technology Process of tert-Butyl-dimethyl-(6-phenoxy-6H-5-oxa-11-thia-benzo[a]fluoren-9-yloxy)-silane

There total 8 articles about tert-Butyl-dimethyl-(6-phenoxy-6H-5-oxa-11-thia-benzo[a]fluoren-9-yloxy)-silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 188824-43-3
9-(tert-Butyl-dimethyl-silanyloxy)-6H-5-oxa-11-thia-benzo[a]fluoren-6-ol

: 108-95-2,27073-41-2
phenol

: 188824-44-4
tert-Butyl-dimethyl-(6-phenoxy-6H-5-oxa-11-thia-benzo[a]fluoren-9-yloxy)-silane

Guidance literature:: In chlorobenzene; for 2.5h; Heating;
DOI:10.1021/jm970688z

Reference yield:

: 90-02-8
salicylaldehyde

: 188824-44-4
tert-Butyl-dimethyl-(6-phenoxy-6H-5-oxa-11-thia-benzo[a]fluoren-9-yloxy)-silane

Guidance literature:: Multi-step reaction with 6 steps

1: 83 percent / Et₃N / ethanol; CH₂Cl₂ / 0.5 h / Ambient temperature

2: DDQ / 1,2-dichloro-ethane / 80 °C

3: ethanethiol, AlCl₃ / CH₂Cl₂ / 5 h / Ambient temperature

4: Et₃N / CH₂Cl₂ / 5 h / Ambient temperature

5: 49 percent / DIBAL-H / toluene / -100 - -70 °C

6: 93 percent / chlorobenzene / 2.5 h / Heating

With aluminium trichloride; diisobutylaluminium hydride; triethylamine; 2,3-dicyano-5,6-dichloro-p-benzoquinone; ethanethiol; In ethanol; dichloromethane; 1,2-dichloro-ethane; chlorobenzene; toluene;
DOI:10.1021/jm970688z

Reference yield:

: 111359-29-6
6-methoxy-N,N-dimethylbenzo[b]thiophen-2-amine

: 188824-44-4
tert-Butyl-dimethyl-(6-phenoxy-6H-5-oxa-11-thia-benzo[a]fluoren-9-yloxy)-silane

Guidance literature:: Multi-step reaction with 7 steps

1: 81 percent / 1N aq. HCl / tetrahydrofuran / 12 h / Heating

2: 83 percent / Et₃N / ethanol; CH₂Cl₂ / 0.5 h / Ambient temperature

3: DDQ / 1,2-dichloro-ethane / 80 °C

4: ethanethiol, AlCl₃ / CH₂Cl₂ / 5 h / Ambient temperature

5: Et₃N / CH₂Cl₂ / 5 h / Ambient temperature

6: 49 percent / DIBAL-H / toluene / -100 - -70 °C

7: 93 percent / chlorobenzene / 2.5 h / Heating

With hydrogenchloride; aluminium trichloride; diisobutylaluminium hydride; triethylamine; 2,3-dicyano-5,6-dichloro-p-benzoquinone; ethanethiol; In tetrahydrofuran; ethanol; dichloromethane; 1,2-dichloro-ethane; chlorobenzene; toluene;
DOI:10.1021/jm970688z