di-(p-chlorophenyl)phosphinic azide

Base Information

• Chemical Name: di-(p-chlorophenyl)phosphinic azide
• CAS No.: 4129-19-5
• Molecular Formula: C₁₂H₈Cl₂N₃OP
• Molecular Weight: 312.095
• Mol file: 4129-19-5.mol

Synonyms:di-(p-chlorophenyl)phosphinic azide

Chemical Property of di-(p-chlorophenyl)phosphinic azide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of di-(p-chlorophenyl)phosphinic azide

There total 4 articles about di-(p-chlorophenyl)phosphinic azide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

Bis(4-chlorophenyl)phosphinyl chloride (4129-39-9) → di-(p-chlorophenyl)phosphinic azide (4129-19-5)

Guidance literature:

With sodium azide; In acetonitrile; for 16h; Ambient temperature;

DOI:10.1016/0040-4020(82)80240-8

Reference yield:

bis(4-chlorophenyl)phosphine oxide (15948-60-4) → di-(p-chlorophenyl)phosphinic azide (4129-19-5)

Guidance literature:

Multi-step reaction with 3 steps

1: 64 percent / H₂O₂ / CH₂Cl₂ / 24 h

2: SOCl₂ / 2 h / Heating

3: 70 percent / sodium azide / acetonitrile / 16 h / Ambient temperature

With thionyl chloride; sodium azide; dihydrogen peroxide; In dichloromethane; acetonitrile;

DOI:10.1016/0040-4020(82)80240-8

Reference yield:

NSC 59743 (13119-01-2) → di-(p-chlorophenyl)phosphinic azide (4129-19-5)

Guidance literature:

Multi-step reaction with 2 steps

1: SOCl₂ / 2 h / Heating

2: 70 percent / sodium azide / acetonitrile / 16 h / Ambient temperature

With thionyl chloride; sodium azide; In acetonitrile;

DOI:10.1016/0040-4020(82)80240-8

upstream raw materials:

Bis(4-chlorophenyl)phosphinyl chloride

bis(4-chlorophenyl)phosphine oxide

NSC 59743

Downstream raw materials:

methyl bis(4-chlorophenyl)phosphinate

methyl NP-di(p-chlorophenyl)phosphonamidate

methyl-N-phenyl-P-p-chlorophenylphosphonamidate

Refernces