allyl 4-O-benzyl-3-O-<(3RS)-3-(benzyloxy)decanyl>-2-deoxy-2-triflouroacetamido-α-D-glucopyranoside

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Chemical Name:allyl 4-O-benzyl-3-O-<(3RS)-3-(benzyloxy)decanyl>-2-deoxy-2-triflouroacetamido-α-D-glucopyranoside
CAS No.:137042-24-1
Molecular Formula:C₃₅H₄₈F₃NO₇
Molecular Weight:651.764
Hs Code.:

Synonyms:allyl 4-O-benzyl-3-O-<(3RS)-3-(benzyloxy)decanyl>-2-deoxy-2-triflouroacetamido-α-D-glucopyranoside

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Chemical Property of allyl 4-O-benzyl-3-O-<(3RS)-3-(benzyloxy)decanyl>-2-deoxy-2-triflouroacetamido-α-D-glucopyranoside

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Technology Process of allyl 4-O-benzyl-3-O-<(3RS)-3-(benzyloxy)decanyl>-2-deoxy-2-triflouroacetamido-α-D-glucopyranoside

There total 6 articles about allyl 4-O-benzyl-3-O-<(3RS)-3-(benzyloxy)decanyl>-2-deoxy-2-triflouroacetamido-α-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 55.0%

: 137042-23-0
Acetic acid (2R,3S,4R,5R,6S)-6-allyloxy-3-benzyloxy-4-(3-benzyloxy-decyloxy)-5-(2,2,2-trifluoro-acetylamino)-tetrahydro-pyran-2-ylmethyl ester

: 137042-24-1
allyl 4-O-benzyl-3-O-<(3RS)-3-(benzyloxy)decanyl>-2-deoxy-2-triflouroacetamido-α-D-glucopyranoside

Guidance literature:: With ammonium hydroxide; In methanol; for 15h;
DOI:10.1016/0008-6215(91)89007-3

Reference yield:

: 139573-88-9
(+/-)-3-benzyloxy-1-hydroxydecane

: 137042-24-1
allyl 4-O-benzyl-3-O-<(3RS)-3-(benzyloxy)decanyl>-2-deoxy-2-triflouroacetamido-α-D-glucopyranoside

Guidance literature:: Multi-step reaction with 6 steps

1: 91 percent / Et₃N / CH₂Cl₂ / 1 h / Ambient temperature

2: 49 percent / NaH / dimethylformamide / 3 h / 20 - 25 °C

3: 99 percent / 80percent AcOH / 0.5 h / 60 °C

4: 87 percent / pyridine / tetrahydrofuran / 1) 30 min, 0 - 5 deg C, 2) 15h, 25 deg C

5: 31 percent / CF₃SO₃H / CH₂Cl₂ / 15 h

6: 55 percent / NH₄OH / methanol / 15 h

With pyridine; ammonium hydroxide; trifluorormethanesulfonic acid; sodium hydride; acetic acid; triethylamine; In tetrahydrofuran; methanol; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1016/0008-6215(91)89007-3

Reference yield:

: 132792-08-6
(+/-)-3-benzyloxy-1-methanesulfonyloxydecane

: 137042-24-1
allyl 4-O-benzyl-3-O-<(3RS)-3-(benzyloxy)decanyl>-2-deoxy-2-triflouroacetamido-α-D-glucopyranoside

Guidance literature:: Multi-step reaction with 5 steps

1: 49 percent / NaH / dimethylformamide / 3 h / 20 - 25 °C

2: 99 percent / 80percent AcOH / 0.5 h / 60 °C

3: 87 percent / pyridine / tetrahydrofuran / 1) 30 min, 0 - 5 deg C, 2) 15h, 25 deg C

4: 31 percent / CF₃SO₃H / CH₂Cl₂ / 15 h

5: 55 percent / NH₄OH / methanol / 15 h

With pyridine; ammonium hydroxide; trifluorormethanesulfonic acid; sodium hydride; acetic acid; In tetrahydrofuran; methanol; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1016/0008-6215(91)89007-3