1,5-anhydro-6-O-(tert-butyldiphenylsilyl)-2-deoxy-3,4-di-O-methyl-D-arabino-hex-1-enitol

Base Information

Chemical Name:1,5-anhydro-6-O-(tert-butyldiphenylsilyl)-2-deoxy-3,4-di-O-methyl-D-arabino-hex-1-enitol
CAS No.:1449682-70-5
Molecular Formula:C₂₄H₃₂O₄Si
Molecular Weight:412.601
Hs Code.:

Synonyms:1,5-anhydro-6-O-(tert-butyldiphenylsilyl)-2-deoxy-3,4-di-O-methyl-D-arabino-hex-1-enitol

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Chemical Property of 1,5-anhydro-6-O-(tert-butyldiphenylsilyl)-2-deoxy-3,4-di-O-methyl-D-arabino-hex-1-enitol

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Technology Process of 1,5-anhydro-6-O-(tert-butyldiphenylsilyl)-2-deoxy-3,4-di-O-methyl-D-arabino-hex-1-enitol

There total 1 articles about 1,5-anhydro-6-O-(tert-butyldiphenylsilyl)-2-deoxy-3,4-di-O-methyl-D-arabino-hex-1-enitol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 87316-22-1
(2R,3S,4R)-2-(((tert-butyldiphenylsilyl)oxy)methyl)-3,4-dihydro-2H-pyran-3,4-diol

: 74-88-4
methyl iodide

: 1449682-70-5
1,5-anhydro-6-O-(tert-butyldiphenylsilyl)-2-deoxy-3,4-di-O-methyl-D-arabino-hex-1-enitol

Guidance literature:: With silver(l) oxide; In acetone; at 20 ℃; Inert atmosphere; Darkness;
DOI:10.1002/chem.201301230

Reference yield: 39.0%

: 1449682-70-5
1,5-anhydro-6-O-(tert-butyldiphenylsilyl)-2-deoxy-3,4-di-O-methyl-D-arabino-hex-1-enitol

: C₂₄H₃₂O₅Si

Guidance literature:: With aluminum oxide; pyridinium chlorochromate; In 1,2-dichloro-ethane; at -20 ℃; for 5h; Inert atmosphere; Reflux;
DOI:10.1021/ol502103b

Reference yield:

: 1449682-70-5
1,5-anhydro-6-O-(tert-butyldiphenylsilyl)-2-deoxy-3,4-di-O-methyl-D-arabino-hex-1-enitol

: C₂₆H₃₆O₅Si

Guidance literature:: Multi-step reaction with 2 steps

1: aluminum oxide; pyridinium chlorochromate / 1,2-dichloro-ethane / 5 h / -20 °C / Inert atmosphere; Reflux

2: tetrahydrofuran / 2 h / -78 °C / Inert atmosphere

With aluminum oxide; pyridinium chlorochromate; In tetrahydrofuran; 1,2-dichloro-ethane;
DOI:10.1021/ol502103b