bromo-η5-1,2,3,4,5-penta-[4-(triisopropylsilylacetylene)phenyl]cyclopentadienyl dicarbonyl ruthenium(II)

Base Information

Chemical Name:bromo-η5-1,2,3,4,5-penta-[4-(triisopropylsilylacetylene)phenyl]cyclopentadienyl dicarbonyl ruthenium(II)
CAS No.:899827-59-9
Molecular Formula:C₉₂H₁₂₅BrO₂RuSi₅
Molecular Weight:1584.4
Hs Code.:

Synonyms:bromo-η5-1,2,3,4,5-penta-[4-(triisopropylsilylacetylene)phenyl]cyclopentadienyl dicarbonyl ruthenium(II)

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Chemical Property of bromo-η5-1,2,3,4,5-penta-[4-(triisopropylsilylacetylene)phenyl]cyclopentadienyl dicarbonyl ruthenium(II)

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Technology Process of bromo-η5-1,2,3,4,5-penta-[4-(triisopropylsilylacetylene)phenyl]cyclopentadienyl dicarbonyl ruthenium(II)

There total 1 articles about bromo-η5-1,2,3,4,5-penta-[4-(triisopropylsilylacetylene)phenyl]cyclopentadienyl dicarbonyl ruthenium(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

: 899827-58-8
1-bromo-1,2,3,4,5-penta-(4-(triisopropylsilylacetylene)phenyl)cyclopentadiene

: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

: 899827-59-9
bromo-η5-1,2,3,4,5-penta-[4-(triisopropylsilylacetylene)phenyl]cyclopentadienyl dicarbonyl ruthenium(II)

Guidance literature:: In not given; chromy.;
DOI:10.1039/b603508f

Reference yield: 30.0%

: potassium hydrotris(indazol-1-yl)borate

: 899827-59-9
bromo-η5-1,2,3,4,5-penta-[4-(triisopropylsilylacetylene)phenyl]cyclopentadienyl dicarbonyl ruthenium(II)

: [Ru(1,2,3,4,5-penta(4-(tri(isopropyl)silyl)ethynylphenyl)cyclopentadiene)(tris(indazolyl)borate)]

Guidance literature:: In not given;
DOI:10.1039/b603508f

Reference yield: 17.0%

: 899827-59-9
bromo-η5-1,2,3,4,5-penta-[4-(triisopropylsilylacetylene)phenyl]cyclopentadienyl dicarbonyl ruthenium(II)

: potassium hydrotris[6-(ethoxycarbonyl)indazol-1-yl]borate

: η5-1,2,3,4,5-penta-[4-(triisopropylsilylacetylene)phenyl]cyclopentadienyl hydrotris[6-(ethoxycarbonyl)indazol-1-yl]borate ruthenium(II)

Guidance literature:: In N,N-dimethyl-formamide; acetonitrile; other Radiation; (under Ar, Schlenk); Ru-complex and B-compound heated in sealed tube at 150°C under microwave irradiation for 10 min in MeCN-DMF; evapd. under vac., ppt. purified by column chromy. SiO2 with cyclohexane-CH2Cl2 80 %;
DOI:10.1039/b605509e