4-{2-[3,4-bis-(tert-butyldimethyl-silanyloxy)-phenyl]-vinyl}-benzaldehyde

Base Information

Chemical Name:4-{2-[3,4-bis-(tert-butyldimethyl-silanyloxy)-phenyl]-vinyl}-benzaldehyde
CAS No.:950745-58-1
Molecular Formula:C₂₇H₄₀O₃Si₂
Molecular Weight:468.784
Hs Code.:

Synonyms:4-{2-[3,4-bis-(tert-butyldimethyl-silanyloxy)-phenyl]-vinyl}-benzaldehyde

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Chemical Property of 4-{2-[3,4-bis-(tert-butyldimethyl-silanyloxy)-phenyl]-vinyl}-benzaldehyde

Chemical Property:

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Technology Process of 4-{2-[3,4-bis-(tert-butyldimethyl-silanyloxy)-phenyl]-vinyl}-benzaldehyde

There total 8 articles about 4-{2-[3,4-bis-(tert-butyldimethyl-silanyloxy)-phenyl]-vinyl}-benzaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 950745-54-7
trans-3,4-di-(tert-butyldimethylsilanyloxy)-4'-(methoxycarbonyl)stilbene

: 950745-56-9
C₂₇H₄₂Si₂O₃

: 950745-58-1
4-{2-[3,4-bis-(tert-butyldimethyl-silanyloxy)-phenyl]-vinyl}-benzaldehyde

Guidance literature:: With diisobutylaluminium hydride; In dichloromethane; at -78 ℃;
DOI:10.1016/j.bmcl.2007.06.016

Reference yield:

: [4-(methoxycarbonyl)benzyl]triphenylphosphonium iodide

: 950745-58-1
4-{2-[3,4-bis-(tert-butyldimethyl-silanyloxy)-phenyl]-vinyl}-benzaldehyde

Guidance literature:: Multi-step reaction with 2 steps

1: 69 percent / NaH / CH₂Cl₂ / 0 °C

2: DIBAL-H / CH₂Cl₂ / -78 °C

With sodium hydride; diisobutylaluminium hydride; In dichloromethane; 1: Wittig reaction;
DOI:10.1016/j.bmcl.2007.06.016

Reference yield:

: 1642-81-5
p-(chloromethyl)benzoic acid

: 950745-58-1
4-{2-[3,4-bis-(tert-butyldimethyl-silanyloxy)-phenyl]-vinyl}-benzaldehyde

Guidance literature:: Multi-step reaction with 5 steps

1: 87 percent / K₂CO₃ / acetone

2: 89 percent / NaI / acetone / Heating

3: 99 percent / diethyl ether / Heating

4: 69 percent / NaH / CH₂Cl₂ / 0 °C

5: DIBAL-H / CH₂Cl₂ / -78 °C

With sodium hydride; diisobutylaluminium hydride; potassium carbonate; sodium iodide; In diethyl ether; dichloromethane; acetone; 4: Wittig reaction;
DOI:10.1016/j.bmcl.2007.06.016