methyl 2-O-allyl-3-O-benzoyl-4-O-methanesulfonyl-6-O-trityl-α-D-allopyranoside

Base Information

Chemical Name:methyl 2-O-allyl-3-O-benzoyl-4-O-methanesulfonyl-6-O-trityl-α-D-allopyranoside
CAS No.:108966-91-2
Molecular Formula:C₃₇H₃₈O₉S
Molecular Weight:658.769
Hs Code.:

Synonyms:methyl 2-O-allyl-3-O-benzoyl-4-O-methanesulfonyl-6-O-trityl-α-D-allopyranoside

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of methyl 2-O-allyl-3-O-benzoyl-4-O-methanesulfonyl-6-O-trityl-α-D-allopyranoside

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Technology Process of methyl 2-O-allyl-3-O-benzoyl-4-O-methanesulfonyl-6-O-trityl-α-D-allopyranoside

There total 5 articles about methyl 2-O-allyl-3-O-benzoyl-4-O-methanesulfonyl-6-O-trityl-α-D-allopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: 124-63-0
methanesulfonyl chloride

: 108966-90-1
methyl 2-O-allyl-3-O-benzoyl-6-O-trityl-α-D-allopyranoside

: 108966-91-2
methyl 2-O-allyl-3-O-benzoyl-4-O-methanesulfonyl-6-O-trityl-α-D-allopyranoside

Guidance literature:: In dichloromethane; at 0 ℃; for 1h;
DOI:10.1016/S0040-4020(01)87284-7

Reference yield:

: 108966-88-7
methyl 2-O-allyl-3-O-benzoyl-4,6-O-benzylidene-α-D-allopyranoside

: 108966-91-2
methyl 2-O-allyl-3-O-benzoyl-4-O-methanesulfonyl-6-O-trityl-α-D-allopyranoside

Guidance literature:: Multi-step reaction with 3 steps

1: 91 percent / 70percent aq. acetic acid / 4 h / 80 °C

2: 90 percent / pyridine / 2 h / 80 °C

3: 87 percent / CH₂Cl₂ / 1 h / 0 °C

With acetic acid; In pyridine; dichloromethane;
DOI:10.1016/S0040-4020(01)87284-7

Reference yield:

: 3162-96-7,4148-58-7,4153-17-7,4288-93-1,5328-47-2,6988-39-2,13566-32-0,14155-23-8,27994-50-9,37093-57-5,37093-59-7,57701-27-6,59168-66-0,64552-06-3,65391-13-1,65391-14-2,65530-26-9,66512-65-0,71117-36-7,71117-37-8,71117-41-4,72904-85-9,74560-56-8,79549-74-9,86783-81-5,96093-51-5,98633-13-7,110415-35-5,110415-36-6,110850-29-8,124020-29-7,126924-12-7,129263-21-4,131433-03-9,145920-49-6,146863-04-9
(4aS,6R,7S,8R,8aR)-6-Methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxine-7,8-diol

: 108966-91-2
methyl 2-O-allyl-3-O-benzoyl-4-O-methanesulfonyl-6-O-trityl-α-D-allopyranoside

Guidance literature:: Multi-step reaction with 5 steps

1: 1.) dibutyltin oxide / 1.) methanol, reflux, 90 min; 2.) DMF, 1 h, 100 deg C

2: 90 percent / CH₂Cl₂ / Ambient temperature

3: 91 percent / 70percent aq. acetic acid / 4 h / 80 °C

4: 90 percent / pyridine / 2 h / 80 °C

5: 87 percent / CH₂Cl₂ / 1 h / 0 °C

With di(n-butyl)tin oxide; acetic acid; In pyridine; dichloromethane;
DOI:10.1016/S0040-4020(01)87284-7