cis,trans-dicarbonylbis(triethylphosphine)(dithioformate-κ2-S)manganese

Base Information

• Chemical Name: cis,trans-dicarbonylbis(triethylphosphine)(dithioformate-κ2-S)manganese
• CAS No.: 121846-72-8
• Molecular Formula: C₁₅H₃₁MnO₂P₂S₂
• Molecular Weight: 424.427
• Mol file: 121846-72-8.mol

Synonyms:cis,trans-dicarbonylbis(triethylphosphine)(dithioformate-κ2-S)manganese

Chemical Property of cis,trans-dicarbonylbis(triethylphosphine)(dithioformate-κ2-S)manganese

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of cis,trans-dicarbonylbis(triethylphosphine)(dithioformate-κ2-S)manganese

There total 1 articles about cis,trans-dicarbonylbis(triethylphosphine)(dithioformate-κ2-S)manganese which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

sodium tetrahydroborate (16940-66-2) + Mn(P(C2H5)3)2(CO)2S2CP(C2H5)3(1+)*ClO4(1-)=Mn(P(C2H5)3)2(CO)2S2CP(C2H5)3ClO4 → cis,trans-dicarbonylbis(triethylphosphine)(dithioformate-κ2-S)manganese (121846-72-8) + triethylphosphine (554-70-1)

Guidance literature:

In ethanol; dichloromethane; Addn. of a NaBH4 soln. (EtOH) to a stirred soln. of Mn-complex in CH2Cl2 under N2, stirring (1.5 h), colour turns from deep blue to bright red.; Evapn. of solvent in vac., pumping for 1 h to eleminate the free phosphine, extg. of red solid (hexane), filtn., addn. of EtOH, slow evapn. in vac., elem. anal.;

upstream raw materials:

sodium tetrahydroborate