2,7-bis-(5-pentafluorobenzoyl-thiophene-2-yl)-benzo[1,2-b:6,5-b']dithiophene-4,5-bis(ethyleneoxolane)

Base Information

Chemical Name:2,7-bis-(5-pentafluorobenzoyl-thiophene-2-yl)-benzo[1,2-b:6,5-b']dithiophene-4,5-bis(ethyleneoxolane)
CAS No.:1422378-75-3
Molecular Formula:C₃₆H₁₄F₁₀O₆S₄
Molecular Weight:860.752
Hs Code.:

Synonyms:2,7-bis-(5-pentafluorobenzoyl-thiophene-2-yl)-benzo[1,2-b:6,5-b']dithiophene-4,5-bis(ethyleneoxolane)

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Chemical Property of 2,7-bis-(5-pentafluorobenzoyl-thiophene-2-yl)-benzo[1,2-b:6,5-b']dithiophene-4,5-bis(ethyleneoxolane)

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Technology Process of 2,7-bis-(5-pentafluorobenzoyl-thiophene-2-yl)-benzo[1,2-b:6,5-b']dithiophene-4,5-bis(ethyleneoxolane)

There total 7 articles about 2,7-bis-(5-pentafluorobenzoyl-thiophene-2-yl)-benzo[1,2-b:6,5-b']dithiophene-4,5-bis(ethyleneoxolane) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 51.9%

pentafluorobenzoylchloride: 2251-50-5
pentafluorobenzoylchloride

: 1261169-86-1
2,7-bis-(thiophene-2-yl)-benzo[2,1-b:3,4-b']dithiazole-4,5-bis(ethyleneoxolane)

: 1422378-75-3
2,7-bis-(5-pentafluorobenzoyl-thiophene-2-yl)-benzo[1,2-b:6,5-b']dithiophene-4,5-bis(ethyleneoxolane)

Guidance literature:: 2,7-bis-(thiophene-2-yl)-benzo[2,1-b:3,4-b']dithiazole-4,5-bis(ethyleneoxolane); With n-butyllithium; In tetrahydrofuran; hexane; for 1h; Inert atmosphere; Cooling with acetone-dry ice;

pentafluorobenzoylchloride; In tetrahydrofuran; hexane;

Reference yield: 35.5%

pentafluorobenzoylchloride: 2251-50-5
pentafluorobenzoylchloride

: 1261169-86-1
2,7-bis-(thiophene-2-yl)-benzo[2,1-b:3,4-b']dithiazole-4,5-bis(ethyleneoxolane)

: 1422378-75-3
2,7-bis-(5-pentafluorobenzoyl-thiophene-2-yl)-benzo[1,2-b:6,5-b']dithiophene-4,5-bis(ethyleneoxolane)

: 1422378-80-0
2-(5-pentafluorobenzoyl-thiophene-2-yl)-7-(thiophene-2-yl)-benzo[2,1-b:3,4-b']dithiazole-4,5-bis(ethyleneoxolane)

Guidance literature:: 2,7-bis-(thiophene-2-yl)-benzo[2,1-b:3,4-b']dithiazole-4,5-bis(ethyleneoxolane); With n-butyllithium; In tetrahydrofuran; hexane; for 0.416667h; Inert atmosphere; Cooling with acetone-dry ice;

pentafluorobenzoylchloride; In tetrahydrofuran; hexane; for 1h;

Reference yield:

: 1258459-49-2
2,5-dibromo-benzo-[2,1-b:3,4-b′]dithiophene-7,8-quinone

: 1422378-75-3
2,7-bis-(5-pentafluorobenzoyl-thiophene-2-yl)-benzo[1,2-b:6,5-b']dithiophene-4,5-bis(ethyleneoxolane)

Guidance literature:: Multi-step reaction with 3 steps

1.1: toluene-4-sulfonic acid / toluene / Reflux

2.1: tetrakis(triphenylphosphine) palladium⁽⁰⁾ / N,N-dimethyl-formamide / 153 °C / Inert atmosphere

3.1: n-butyllithium / tetrahydrofuran; hexane / 0.42 h / Inert atmosphere; Cooling with acetone-dry ice

3.2: 1 h

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; n-butyllithium; toluene-4-sulfonic acid; In tetrahydrofuran; hexane; N,N-dimethyl-formamide; toluene;