tert-Butyl-5-acetamido-2,6-anhydro-4,7,8,9-tetra-O-benzyl-3,5-didesoxy-2-C-<(methylsulfonyloxy)methyl>-D-erythro-L-manno-nononat

Base Information

Chemical Name:tert-Butyl-5-acetamido-2,6-anhydro-4,7,8,9-tetra-O-benzyl-3,5-didesoxy-2-C-<(methylsulfonyloxy)methyl>-D-erythro-L-manno-nononat
CAS No.:138320-89-5
Molecular Formula:C₄₅H₅₅NO₁₁S
Molecular Weight:817.998
Hs Code.:

Synonyms:tert-Butyl-5-acetamido-2,6-anhydro-4,7,8,9-tetra-O-benzyl-3,5-didesoxy-2-C-<(methylsulfonyloxy)methyl>-D-erythro-L-manno-nononat

Suppliers and Price of tert-Butyl-5-acetamido-2,6-anhydro-4,7,8,9-tetra-O-benzyl-3,5-didesoxy-2-C-<(methylsulfonyloxy)methyl>-D-erythro-L-manno-nononat

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of tert-Butyl-5-acetamido-2,6-anhydro-4,7,8,9-tetra-O-benzyl-3,5-didesoxy-2-C-<(methylsulfonyloxy)methyl>-D-erythro-L-manno-nononat

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of tert-Butyl-5-acetamido-2,6-anhydro-4,7,8,9-tetra-O-benzyl-3,5-didesoxy-2-C-<(methylsulfonyloxy)methyl>-D-erythro-L-manno-nononat

There total 1 articles about tert-Butyl-5-acetamido-2,6-anhydro-4,7,8,9-tetra-O-benzyl-3,5-didesoxy-2-C-<(methylsulfonyloxy)methyl>-D-erythro-L-manno-nononat which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

: 138320-80-6,138320-83-9
tert-Butyl-5-acetamido-2,6-anhydro-4,7,8,9-tetra-O-benzyl-3,5-didesoxy-2-C-(hydroxymethyl)-D-erythro-L-manno-nononat

: 124-63-0
methanesulfonyl chloride

: 138320-89-5
tert-Butyl-5-acetamido-2,6-anhydro-4,7,8,9-tetra-O-benzyl-3,5-didesoxy-2-C-<(methylsulfonyloxy)methyl>-D-erythro-L-manno-nononat

Guidance literature:: With triethylamine; In dichloromethane; at 0 ℃; for 6h;
DOI:10.1002/hlca.19910740716

Reference yield: 75.0%

: 138320-89-5
tert-Butyl-5-acetamido-2,6-anhydro-4,7,8,9-tetra-O-benzyl-3,5-didesoxy-2-C-<(methylsulfonyloxy)methyl>-D-erythro-L-manno-nononat

: tert-Butyl-5-acetamido-2,6-anhydro-2-C-(azidomethyl)-4,7,8,9-tetra-O-benzyl-3,5-didesoxy-D-erythro-L-manno-nononat

Guidance literature:: With sodium azide; In N,N,N,N,N,N-hexamethylphosphoric triamide; at 100 ℃; for 24h;
DOI:10.1002/hlca.19910740716

Reference yield:

: 138320-89-5
tert-Butyl-5-acetamido-2,6-anhydro-4,7,8,9-tetra-O-benzyl-3,5-didesoxy-2-C-<(methylsulfonyloxy)methyl>-D-erythro-L-manno-nononat

: 5-Amino-2,6-anhydro-2-C-(azidomethyl)-4,7,8,9-tetra-O-benzyl-3,5-didesoxy-D-erythro-L-manno-nonono-1,5-lactam

Guidance literature:: Multi-step reaction with 2 steps

1: 75 percent / NaN₃ / hexamethylphosphoric acid triamide / 24 h / 100 °C

2: 50 percent / NaH / dimethylformamide / 24 h / Ambient temperature

With sodium azide; sodium hydride; In N,N,N,N,N,N-hexamethylphosphoric triamide; N,N-dimethyl-formamide;
DOI:10.1002/hlca.19910740716