Cobalt,bis(pyridine)bis(thiocyanato-N)-, (T-4)- (9CI)

Base Information

• Chemical Name: Cobalt,bis(pyridine)bis(thiocyanato-N)-, (T-4)- (9CI)
• CAS No.: 15613-11-3
• Molecular Formula: C12H10 Co N4 S2
• Molecular Weight: 333.363

Synonyms:Cobalt,bis(isothiocyanato)bis(pyridine)- (8CI); Cobalt, diisothiocyanatobis(pyridine)-(7CI); Bis(isothiocyanato)bis(pyridine)cobalt; NSC 250945

Chemical Property of Cobalt,bis(pyridine)bis(thiocyanato-N)-, (T-4)- (9CI)

Chemical Property:

• Boiling Point: 106.4°Cat760mmHg
• Flash Point: 4.4°C
• Density: g/cm³

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Cobalt,bis(pyridine)bis(thiocyanato-N)-, (T-4)- (9CI)

There total 1 articles about Cobalt,bis(pyridine)bis(thiocyanato-N)-, (T-4)- (9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

[Co(py)4(SCN)2] (14882-22-5,15727-35-2) → pyridine (110-86-1) + {Co(NCS)2py2} (15613-11-3)

Guidance literature:

In acetone; dissociation in acetonic solution under formation of (Co(NCS)2(C5H5N)2) and pyridine;; determination at light-absorptions-messurements;;

Reference yield:

{Co(NCS)2py2} (15613-11-3) → cobalt(II) thiocyanate (3017-60-5)

Guidance literature:

In neat (no solvent); formation of Co(SCN)2 at heating in vac. at 300°C;;

DOI:10.1021/ja01302a019

Reference yield:

p-tolyl mercury thiocyanate + {Co(NCS)2py2} (15613-11-3) → (C5H5N)2(SCN)2Co(NCS)2(HgC6H4CH3)2

Guidance literature:

In ethanol; educts in molar ratio=2:1 were stirred in EtOH for 72 h; ppt. filtered, washed with EtOH, dried in vac.; crystd. from acetone/EtOH; elem. anal.;

DOI:10.1016/S0277-5387(00)81055-4

upstream raw materials:

[Co(py)₄(SCN)₂]

Downstream raw materials:

cobalt(II) thiocyanate

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