(R)-tert-butyl((4-chloro-6-iodohept-6-en-1-yl)oxy)diphenylsilane

Base Information

• Chemical Name: (R)-tert-butyl((4-chloro-6-iodohept-6-en-1-yl)oxy)diphenylsilane
• CAS No.: 1191268-95-7
• Molecular Formula: C₂₃H₃₀ClIOSi
• Molecular Weight: 512.934
• Mol file: 1191268-95-7.mol

Synonyms:(R)-tert-butyl((4-chloro-6-iodohept-6-en-1-yl)oxy)diphenylsilane

Chemical Property of (R)-tert-butyl((4-chloro-6-iodohept-6-en-1-yl)oxy)diphenylsilane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (R)-tert-butyl((4-chloro-6-iodohept-6-en-1-yl)oxy)diphenylsilane

There total 1 articles about (R)-tert-butyl((4-chloro-6-iodohept-6-en-1-yl)oxy)diphenylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

C23H29ClOSi (1191268-97-9) → (R)-tert-butyl((4-chloro-6-iodohept-6-en-1-yl)oxy)diphenylsilane (1191268-95-7)

Guidance literature:

With acetic acid; 9-iodo-9-borabicyclo{3.3.1}nonane; In dichloromethane; at 0 ℃; Inert atmosphere;

DOI:10.1021/ol9016595

Reference yield: 90.0%

4-oxobutyl benzoate (22927-31-7) + (R)-tert-butyl((4-chloro-6-iodohept-6-en-1-yl)oxy)diphenylsilane (1191268-95-7) → C34H43ClO4Si (1192815-37-4)

Guidance literature:

With chromium dichloride; manganese; zirconocene dichloride; 2.9-dimethyl-1,10-phenanthroline; C₂₆H₃₂Cl₂N₂O₄S; N,N,N',N'-tetramethyl-1,8-diaminonaphthalene; lithium chloride; In acetonitrile; at 20 ℃; for 10h; optical yield given as %de; Inert atmosphere;

DOI:10.1021/ja9058475

Reference yield: 87.0%

(R)-tert-butyl((4-chloro-6-iodohept-6-en-1-yl)oxy)diphenylsilane (1191268-95-7) + C44H52O10 (1193375-39-1) → C67H83ClO11Si

Guidance literature:

With chromium dichloride; manganese; zirconocene dichloride; C₂₆H₃₂Cl₂N₂O₄S; lithium chloride; In acetonitrile; at 20 ℃; for 3h; optical yield given as %de; stereoselective reaction;

DOI:10.1021/ja9058487

upstream raw materials:

C₂₃H₂₉ClOSi

Downstream raw materials:

C₃₄H₄₃ClO₄Si

C₆₃H₇₇ClO₁₁SSi

C₃₁H₄₉ClO₃Si₂

C₃₄H₄₃ClO₄Si