18,23-butane-19,22-diylbis(14-{[(2R,3R,4S,5R,6S)-4,5-bis(benzyloxy)-3-(hex-11-ene-7-yloxy)-6-methoxytetrahydro-2H-pyran-2-yl]methyl}-1H-14,15,16-triazole)

Base Information

Chemical Name:18,23-butane-19,22-diylbis(14-{[(2R,3R,4S,5R,6S)-4,5-bis(benzyloxy)-3-(hex-11-ene-7-yloxy)-6-methoxytetrahydro-2H-pyran-2-yl]methyl}-1H-14,15,16-triazole)
CAS No.:859857-38-8
Molecular Formula:C₆₂H₈₀N₆O₁₀
Molecular Weight:1069.35
Hs Code.:

Synonyms:18,23-butane-19,22-diylbis(14-{[(2R,3R,4S,5R,6S)-4,5-bis(benzyloxy)-3-(hex-11-ene-7-yloxy)-6-methoxytetrahydro-2H-pyran-2-yl]methyl}-1H-14,15,16-triazole)

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Chemical Property of 18,23-butane-19,22-diylbis(14-{[(2R,3R,4S,5R,6S)-4,5-bis(benzyloxy)-3-(hex-11-ene-7-yloxy)-6-methoxytetrahydro-2H-pyran-2-yl]methyl}-1H-14,15,16-triazole)

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Technology Process of 18,23-butane-19,22-diylbis(14-{[(2R,3R,4S,5R,6S)-4,5-bis(benzyloxy)-3-(hex-11-ene-7-yloxy)-6-methoxytetrahydro-2H-pyran-2-yl]methyl}-1H-14,15,16-triazole)

There total 3 articles about 18,23-butane-19,22-diylbis(14-{[(2R,3R,4S,5R,6S)-4,5-bis(benzyloxy)-3-(hex-11-ene-7-yloxy)-6-methoxytetrahydro-2H-pyran-2-yl]methyl}-1H-14,15,16-triazole) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 859857-35-5
methyl 6-azido-2,3-di-O-benzyl-6-deoxy-4-O-hex-11-ene-7-yl-α-D-glucopyranoside

: 871-84-1
1,7-Octadiyne

: 859857-38-8
18,23-butane-19,22-diylbis(14-{[(2R,3R,4S,5R,6S)-4,5-bis(benzyloxy)-3-(hex-11-ene-7-yloxy)-6-methoxytetrahydro-2H-pyran-2-yl]methyl}-1H-14,15,16-triazole)

Guidance literature:: With copper diacetate; sodium L-ascorbate; In tert-butyl alcohol; at 20 ℃; for 12h;
DOI:10.1039/b502682b

Reference yield:

: 2695-47-8
6-Bromo-1-hexene

: 859857-38-8
18,23-butane-19,22-diylbis(14-{[(2R,3R,4S,5R,6S)-4,5-bis(benzyloxy)-3-(hex-11-ene-7-yloxy)-6-methoxytetrahydro-2H-pyran-2-yl]methyl}-1H-14,15,16-triazole)

Guidance literature:: Multi-step reaction with 2 steps

1.1: NaH / tetrahydrofuran

1.2: 43 percent / tetrahydrofuran / 3 h / Heating

2.1: 99 percent / aq. sodium ascorbate; Cu(OAc)2 / 2-methyl-propan-2-ol / 12 h / 20 °C

With copper diacetate; sodium hydride; sodium L-ascorbate; In tetrahydrofuran; tert-butyl alcohol;
DOI:10.1039/b502682b

Reference yield:

: 54522-58-6
methyl 6-azido-2,3-di-O-benzyl-6-deoxy-α-D-glucopyranoside

: 859857-38-8
18,23-butane-19,22-diylbis(14-{[(2R,3R,4S,5R,6S)-4,5-bis(benzyloxy)-3-(hex-11-ene-7-yloxy)-6-methoxytetrahydro-2H-pyran-2-yl]methyl}-1H-14,15,16-triazole)

Guidance literature:: Multi-step reaction with 2 steps

1.1: NaH / tetrahydrofuran

1.2: 43 percent / tetrahydrofuran / 3 h / Heating

2.1: 99 percent / aq. sodium ascorbate; Cu(OAc)2 / 2-methyl-propan-2-ol / 12 h / 20 °C

With copper diacetate; sodium hydride; sodium L-ascorbate; In tetrahydrofuran; tert-butyl alcohol;
DOI:10.1039/b502682b