methyl 6-azido-2,3-di-O-benzyl-6-deoxy-4-O-hex-11-ene-7-yl-α-D-glucopyranoside

Base Information

Chemical Name:methyl 6-azido-2,3-di-O-benzyl-6-deoxy-4-O-hex-11-ene-7-yl-α-D-glucopyranoside
CAS No.:859857-35-5
Molecular Formula:C₂₇H₃₅N₃O₅
Molecular Weight:481.592
Hs Code.:

Synonyms:methyl 6-azido-2,3-di-O-benzyl-6-deoxy-4-O-hex-11-ene-7-yl-α-D-glucopyranoside

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Chemical Property of methyl 6-azido-2,3-di-O-benzyl-6-deoxy-4-O-hex-11-ene-7-yl-α-D-glucopyranoside

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Technology Process of methyl 6-azido-2,3-di-O-benzyl-6-deoxy-4-O-hex-11-ene-7-yl-α-D-glucopyranoside

There total 1 articles about methyl 6-azido-2,3-di-O-benzyl-6-deoxy-4-O-hex-11-ene-7-yl-α-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 43.0%

: 2695-47-8
6-Bromo-1-hexene

: 54522-58-6
methyl 6-azido-2,3-di-O-benzyl-6-deoxy-α-D-glucopyranoside

: 859857-35-5
methyl 6-azido-2,3-di-O-benzyl-6-deoxy-4-O-hex-11-ene-7-yl-α-D-glucopyranoside

Guidance literature:: methyl 6-azido-2,3-di-O-benzyl-6-deoxy-α-D-glucopyranoside; With sodium hydride; In tetrahydrofuran;

6-Bromo-1-hexene; In tetrahydrofuran; for 3h; Heating;
DOI:10.1039/b502682b

Reference yield: 99.0%

: 859857-35-5
methyl 6-azido-2,3-di-O-benzyl-6-deoxy-4-O-hex-11-ene-7-yl-α-D-glucopyranoside

: 871-84-1
1,7-Octadiyne

: 859857-38-8
18,23-butane-19,22-diylbis(14-{[(2R,3R,4S,5R,6S)-4,5-bis(benzyloxy)-3-(hex-11-ene-7-yloxy)-6-methoxytetrahydro-2H-pyran-2-yl]methyl}-1H-14,15,16-triazole)

Guidance literature:: With copper diacetate; sodium L-ascorbate; In tert-butyl alcohol; at 20 ℃; for 12h;
DOI:10.1039/b502682b

Reference yield:

: 859857-35-5
methyl 6-azido-2,3-di-O-benzyl-6-deoxy-4-O-hex-11-ene-7-yl-α-D-glucopyranoside

: 859857-43-5
(3R,5S,6R,7S,8R,14(E,Z),21R,22S,23R,24S,26R)-6,7,22,23-tetrakis(benzyloxy)-5,24-dimethoxy-4,9,20,25-tetraoxa-1,28,29,30,37,38-hexaazapentacyclo[34.2.1.1^28,31.0^3,8.0^21,26]tetraconta-14,29,31⁽⁴⁰⁾,36⁽³⁹⁾,37-pentaene

Guidance literature:: Multi-step reaction with 2 steps

1: 99 percent / aq. sodium ascorbate; Cu(OAc)2 / 2-methyl-propan-2-ol / 12 h / 20 °C

2: PhCH=Ru(PCy₃)2Cl₂ / CH₂Cl₂ / Heating

With copper diacetate; sodium L-ascorbate; Grubbs catalyst first generation; In dichloromethane; tert-butyl alcohol;
DOI:10.1039/b502682b