P-(1,1-dimethylethyl)-P-phenylphosphinoselenothioic acid S-[2-(trimethylsilyl)ethyl] ester

Base Information

Chemical Name:P-(1,1-dimethylethyl)-P-phenylphosphinoselenothioic acid S-[2-(trimethylsilyl)ethyl] ester
CAS No.:486429-70-3
Molecular Formula:C₁₅H₂₇PSSeSi
Molecular Weight:377.465
Hs Code.:

Synonyms:P-(1,1-dimethylethyl)-P-phenylphosphinoselenothioic acid S-[2-(trimethylsilyl)ethyl] ester

Suppliers and Price of P-(1,1-dimethylethyl)-P-phenylphosphinoselenothioic acid S-[2-(trimethylsilyl)ethyl] ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of P-(1,1-dimethylethyl)-P-phenylphosphinoselenothioic acid S-[2-(trimethylsilyl)ethyl] ester

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of P-(1,1-dimethylethyl)-P-phenylphosphinoselenothioic acid S-[2-(trimethylsilyl)ethyl] ester

There total 7 articles about P-(1,1-dimethylethyl)-P-phenylphosphinoselenothioic acid S-[2-(trimethylsilyl)ethyl] ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: lithium 2-(trimethylsilyl)ethanethiolate

: 146880-01-5
P-(1,1-dimethylethyl)-P-phenylphosphinoselenoic chloride

: 486429-70-3
P-(1,1-dimethylethyl)-P-phenylphosphinoselenothioic acid S-[2-(trimethylsilyl)ethyl] ester

Guidance literature:: In tetrahydrofuran; hexane; at 0 ℃; for 1h;
DOI:10.1021/jo0484979

Reference yield: 74.0%

: 644-97-3
Dichlorophenylphosphine

: lithium 2-(trimethylsilyl)ethanethiolate

: 486429-70-3
P-(1,1-dimethylethyl)-P-phenylphosphinoselenothioic acid S-[2-(trimethylsilyl)ethyl] ester

Guidance literature:: Dichlorophenylphosphine; t-butylmagnesium halide; In tetrahydrofuran; at -78 ℃; for 1h;

lithium 2-(trimethylsilyl)ethanethiolate; at -78 ℃; for 0.25h;

With selenium; at 2 ℃; for 2h;
DOI:10.1246/cl.2002.914

Reference yield:

: 754-05-2
ethenyltrimethylsilane

: 486429-70-3
P-(1,1-dimethylethyl)-P-phenylphosphinoselenothioic acid S-[2-(trimethylsilyl)ethyl] ester

Guidance literature:: Multi-step reaction with 3 steps

1: 94 percent / 23 / 1 h / Heating

2: 78 percent / EtONa / tetrahydrofuran / 12 h / 20 °C

3: tetrahydrofuran / 0 °C

With sodium ethanolate; 23; In tetrahydrofuran;
DOI:10.1021/jo050576c