(C₅H₅)Re(NO)(P(C₆H₅)3)(CH₂S(CH₃)2)⁽¹⁺⁾*PF₆^(1-)=[(C₅H₅)Re(NO)(P(C₆H₅)3)(CH₂S(CH₃)2)]PF₆

Base Information

• Chemical Name: (C₅H₅)Re(NO)(P(C₆H₅)3)(CH₂S(CH₃)2)⁽¹⁺⁾*PF₆^(1-)=[(C₅H₅)Re(NO)(P(C₆H₅)3)(CH₂S(CH₃)2)]PF₆
• CAS No.: 80136-84-1
• Molecular Formula: C₂₆H₂₈NOPReS*F₆P
• Molecular Weight: 764.725
• Mol file: 80136-84-1.mol

Synonyms:(C₅H₅)Re(NO)(P(C₆H₅)3)(CH₂S(CH₃)2)⁽¹⁺⁾*PF₆^(1-)=[(C₅H₅)Re(NO)(P(C₆H₅)3)(CH₂S(CH₃)2)]PF₆

Chemical Property of (C₅H₅)Re(NO)(P(C₆H₅)3)(CH₂S(CH₃)2)⁽¹⁺⁾*PF₆^(1-)=[(C₅H₅)Re(NO)(P(C₆H₅)3)(CH₂S(CH₃)2)]PF₆

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (C₅H₅)Re(NO)(P(C₆H₅)3)(CH₂S(CH₃)2)⁽¹⁺⁾*PF₆^(1-)=[(C₅H₅)Re(NO)(P(C₆H₅)3)(CH₂S(CH₃)2)]PF₆

There total 2 articles about (C₅H₅)Re(NO)(P(C₆H₅)3)(CH₂S(CH₃)2)⁽¹⁺⁾*PF₆^(1-)=[(C₅H₅)Re(NO)(P(C₆H₅)3)(CH₂S(CH₃)2)]PF₆ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

(η5-C5H5)(Me)(NO)(PPh3)rhenium(II) + dimethylsulfide (75-18-3) + tritylium hexafluorophosphate (437-17-2) → (C5H5)Re(NO)(P(C6H5)3)(CH2S(CH3)2)(1+)*PF6(1-)=[(C5H5)Re(NO)(P(C6H5)3)(CH2S(CH3)2)]PF6 (80136-84-1)

Guidance literature:

In dichloromethane; N2-atmosphere; addn. of Ph3CPF6 to Re-complex (-78°C), stirring (1 h), addn. of Me2S, stirring (-78°C, 15 min), warming to room temp. (during 0.5 h); concn. (vac.), pptn. on hexane addn., filtration, washing (hexanes), crystn. (diffusion of hexanes into CH2Cl2 soln., -20°C); elem. anal.;

Reference yield:

[(η(5)-cyclopentadienyl)Re(NO)(P(C6H5)3)(methylidene)]PF6 (71763-23-0) + dimethylsulfide (75-18-3) → (C5H5)Re(NO)(P(C6H5)3)(CH2S(CH3)2)(1+)*PF6(1-)=[(C5H5)Re(NO)(P(C6H5)3)(CH2S(CH3)2)]PF6 (80136-84-1)

Guidance literature:

In dichloromethane; -78°C; removal of solvent, recrystn. from CH2Cl2/hexane;

DOI:10.1016/S0022-328X(00)81018-9

Reference yield: 97.0%

methylthiol (74-93-1) + (C5H5)Re(NO)(P(C6H5)3)(CH2S(CH3)2)(1+)*PF6(1-)=[(C5H5)Re(NO)(P(C6H5)3)(CH2S(CH3)2)]PF6 (80136-84-1) + sodium hydride (7646-69-7) → (C5H5)Re(NO)(P(C6H5)3)(CH2SCH3) (80136-87-4)

Guidance literature:

In tetrahydrofuran; methanol; N2-atmosphere; bubbling MeSH through NaH suspn. in THF, stirring (45 min), addn. of MeOH and Re-complex, stirring (2 h); solvent removal (reduced pressure), extn. (CH2Cl2), evapn. of extract (N2-stream), extn. (ether), concn., crystn. (-20°C); elem. anal.;

upstream raw materials:

dimethylsulfide

tritylium hexafluorophosphate

[(η(5)-cyclopentadienyl)Re(NO)(P(C6H5)3)(methylidene)]PF6

Downstream raw materials:

{(η5-C5H5)Re(NO)(PPh3)(CH2PPh3)}(+)PF6(-)

(C₅H₅)ReNO{P(C₆H₅)3}(CH₂NC₅H₅)⁽¹⁺⁾*PF₆^(1-)=(C₅H₅)ReNOP(C₆H₅)3CH₂NC₅H₅PF₆

(C₅H₅)Re(NO)(P(C₆H₅)3)(CH₂SCH₃)

(C₅H₅)Re(NO)(P(C₆H₅)3)(CH₂SCH₂C₆H₅)