N-(4-(1,2,2-triphenylvinyl)phenyl)benzenamine

Base Information

• Chemical Name: N-(4-(1,2,2-triphenylvinyl)phenyl)benzenamine
• CAS No.: 1426396-32-8
• Molecular Formula: C₃₂H₂₅N
• Molecular Weight: 423.557
• Mol file: 1426396-32-8.mol

Synonyms:N-(4-(1,2,2-triphenylvinyl)phenyl)benzenamine

Chemical Property of N-(4-(1,2,2-triphenylvinyl)phenyl)benzenamine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N-(4-(1,2,2-triphenylvinyl)phenyl)benzenamine

There total 4 articles about N-(4-(1,2,2-triphenylvinyl)phenyl)benzenamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

1-(4-bromophenyl)triphenylethene (34699-28-0) + aniline (62-53-3) → N-(4-(1,2,2-triphenylvinyl)phenyl)benzenamine (1426396-32-8)

Guidance literature:

With tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; tri-tert-butyl phosphine; sodium t-butanolate; In toluene; at 120 ℃; for 20h; Schlenk technique; Inert atmosphere;

DOI:10.1002/ejoc.202100199

Reference yield:

Diphenylmethane (101-81-5) → N-(4-(1,2,2-triphenylvinyl)phenyl)benzenamine (1426396-32-8)

Guidance literature:

Multi-step reaction with 3 steps

1.1: n-butyllithium / tetrahydrofuran; hexane / 2 h / -5 °C / Inert atmosphere

1.2: 10 h / 20 °C / Inert atmosphere

2.1: toluene-4-sulfonic acid / toluene / 12 h / Inert atmosphere; Reflux

3.1: tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; sodium t-butanolate; tri-tert-butyl phosphine / toluene / 24 h / 110 °C / Inert atmosphere

With tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; n-butyllithium; tri-tert-butyl phosphine; toluene-4-sulfonic acid; sodium t-butanolate; In tetrahydrofuran; hexane; toluene;

DOI:10.1039/c5tb00207a

Reference yield:

diphenylmethyllithium (881-42-5) → N-(4-(1,2,2-triphenylvinyl)phenyl)benzenamine (1426396-32-8)

Guidance literature:

Multi-step reaction with 3 steps

1: tetrahydrofuran / -78 °C / Inert atmosphere

2: toluene-4-sulfonic acid / toluene / Reflux; Inert atmosphere

3: tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; tri-tert-butyl phosphine; potassium tert-butylate / toluene / Inert atmosphere

With tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; tri-tert-butyl phosphine; potassium tert-butylate; toluene-4-sulfonic acid; In tetrahydrofuran; toluene;

DOI:10.1002/adfm.201302114

upstream raw materials:

1-(4-bromophenyl)triphenylethene

aniline

diphenylmethyllithium

Diphenylmethane