Li⁽¹⁺⁾*Al₂Br₇^(1-)=LiAl₂Br₇

Base Information

• Chemical Name: Li⁽¹⁺⁾*Al₂Br₇^(1-)=LiAl₂Br₇
• CAS No.: 51931-76-1
• Molecular Formula: Al₂Br₇*Li
• Molecular Weight: 620.232
• Mol file: 51931-76-1.mol

Synonyms:Li⁽¹⁺⁾*Al₂Br₇^(1-)=LiAl₂Br₇

Chemical Property of Li⁽¹⁺⁾*Al₂Br₇^(1-)=LiAl₂Br₇

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of Li⁽¹⁺⁾*Al₂Br₇^(1-)=LiAl₂Br₇

There total 4 articles about Li⁽¹⁺⁾*Al₂Br₇^(1-)=LiAl₂Br₇ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 10.0%

lithium aluminium tetrahydride (16853-85-3) + aluminum bromide → aluminum hydride (7784-21-6) + Li(1+)*Al2Br7(1-)=LiAl2Br7 (51931-76-1)

Guidance literature:

In benzene; in dry Ar glovebox or in vac. using Schlenk techniques; cold soln. of Al2Br6 in benzene added to suspn. of LiAlH4 in benzene preheated on oil bath (molar ratio of Al2Br6/LiAlH4 was 1:6); soln. addition rate was adjusted so that temp. of mixt. ...; ppt. washed (Et2O); elem. anal.;

DOI:10.1134/S0036023608070048

Reference yield:

lithium aluminium tetrahydride (16853-85-3) + aluminum bromide → aluminium hydride (7784-21-6) + aluminum hydride (7784-21-6) + Li(1+)*Al2Br7(1-)=LiAl2Br7 (51931-76-1)

Guidance literature:

In octane; in dry Ar glovebox or in vac. using Schlenk techniques; cold soln. of Al2Br6 in octane added to suspn. of LiAlH4 in octane preheated on oil bath(molar ratio of Al2Br6/LiAlH4 was 7:6); soln. addition rate was adjuste d so that temp. of mixt. ...; ppt. washed (Et2O); elem. anal.;

DOI:10.1134/S0036023608070048

Reference yield:

lithium aluminium tetrahydride (16853-85-3) + aluminum bromide → aluminium hydride (7784-21-6) + aluminum hydride (7784-21-6) + aluminum hydride (7784-21-6) + Li(1+)*Al2Br7(1-)=LiAl2Br7 (51931-76-1)

Guidance literature:

In n-heptane; in dry Ar glovebox or in vac. using Schlenk techniques; cold soln. of Al2Br6 in heptane added to suspn. of LiAlH4 in heptane preheated on oil bath (molar ratio of Al2Br6/LiAlH4 was 7:6); soln. addition rate was adjusted so that temp. of mixt. ...; ppt. washed (Et2O); elem. anal.;

DOI:10.1134/S0036023608070048

upstream raw materials:

lithium aluminium tetrahydride