(η5-cyclopentadienyl)Fe(CO)2(PPh2BH3)

Base Information

Chemical Name:(η5-cyclopentadienyl)Fe(CO)2(PPh2BH3)
CAS No.:191608-88-5
Molecular Formula:C₁₉H₁₈BFeO₂P
Molecular Weight:375.982
Hs Code.:

Synonyms:(η5-cyclopentadienyl)Fe(CO)2(PPh2BH3)

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Chemical Property of (η5-cyclopentadienyl)Fe(CO)2(PPh2BH3)

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Technology Process of (η5-cyclopentadienyl)Fe(CO)2(PPh2BH3)

There total 4 articles about (η5-cyclopentadienyl)Fe(CO)2(PPh2BH3) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: potassium diphenylphosphanylborohydride

: 12078-28-3,38979-86-1
dicarbonylcyclopentadienyliodoiron(II)

: 191608-88-5
(η5-cyclopentadienyl)Fe(CO)2(PPh2BH3)

Guidance literature:: In tetrahydrofuran; under an inert atm.; by a react. of Fe-contg. compd. with K(PPh2BH3) in THF; according to T. I. Kueckmann et al., Eur. J. Inorg. Chem., 2007, 1989;
DOI:10.1039/c2dt00031h

Reference yield: 66.0%

: {(η5-C5H5)Fe(CO)2(PPh2H)}PF6

: borane tetrahydrofuran

: 19493-09-5
Methylenetriphenylphosphorane

: 191608-88-5
(η5-cyclopentadienyl)Fe(CO)2(PPh2BH3)

Guidance literature:: In tetrahydrofuran; benzene; N2-atmosphere; stirring (room temp, 30 min); evapn. (reduced pressure), chromy. (SiO2, C6H6 / CH2Cl2 = 1 : 1), evapn.(reduced pressure), CH2Cl2 and hexane addn., evapn.; elem. anal.;
DOI:10.1021/om9610152

Reference yield: 50.0%

: 12078-28-3,38979-86-1
dicarbonylcyclopentadienyliodoiron(II)

: Li[(diphenylphosphide)B(hydride)3]

: 191608-88-5
(η5-cyclopentadienyl)Fe(CO)2(PPh2BH3)

Guidance literature:: In tetrahydrofuran; under Ar; a soln. of Fe-contg. compd. (3.29 mmol) in THF was cooled to -30°C; a similarly chilled (-30°C) LiPPh2*BH3 (0.149 M in THF) was added dropwise; the temp. was maintained between -30 and -20°C for 1.5 h; volatile compds. were removed in vac.; the compd. was chromd. on silica supported on frit with Et2O; the soln. vol. was reduced in the vac.; thecompd. was crystd. at -40°C for 2 d; the working-up was repeated in Et2O or toluene; elem. anal.;
DOI:10.1039/b718918d