DICARBONYLCYCLOPENTADIENYLIODOIRON

Base Information

• Chemical Name: DICARBONYLCYCLOPENTADIENYLIODOIRON
• CAS No.: 12078-28-3
• Molecular Formula: C₇H₅FeIO₂
• Molecular Weight: 303.867
• Mol file: 12078-28-3.mol

Synonyms:Iron,dicarbonyl-p-cyclopentadienyliodo- (8CI);Iron, iododicarbonylcyclopentadienyl- (6CI,7CI); Cyclopentadienyldicarbonyliodo iron; Cyclopentadienylirondicarbonyliodide;Dicarbonyl(iodo)cyclopentadienyliron; Dicarbonyl(h-cyclopentadienyl)iodoiron; Dicarbonyl(h5-cyclopentadienyl)iodoiron;Dicarbonyl(h5-cyclopentadienyl)iodoiron(II);Dicarbonyl-p-cyclopentadienyliodoiron;Dicarbonylcyclopentadienyliodoiron; Dicarbonylcyclopentadienyliron iodide;Iodo(cyclopentadienyl)dicarbonyliron; NSC 107230; p-Cyclopentadienyliododicarbonyl iron

Chemical Property of DICARBONYLCYCLOPENTADIENYLIODOIRON

Chemical Property:

• Melting Point: 119-120°C (dec.)
• PSA: 0.00000
• LogP: 1.48870

Purity/Quality:

99% ^*data from raw suppliers

Dicarbonylcyclopentadienyliodoiron(II) 97% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xn
• Statements: 20/21/22
• Safety Statements: 36

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Technology Process of DICARBONYLCYCLOPENTADIENYLIODOIRON

There total 128 articles about DICARBONYLCYCLOPENTADIENYLIODOIRON which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

C5H5Fe(CO)2CH2CHC6H9O(1+)*BF4(1-) (75182-46-6) + sodium iodide (7681-82-5,24359-64-6,41927-88-2,115813-40-6) → dicarbonylcyclopentadienyliodoiron(II) (12078-28-3,38979-86-1) + 2-ethenylcyclohexanone (1122-24-3)

Guidance literature:

In acetone; room temp., 0.5 h;; evapd.; chromy.;;

DOI:10.1021/om00154a021

Reference yield: 77.0%

1,4-C6H4(COFp)2 (119923-98-7) → dicarbonylcyclopentadienyliodoiron(II) (12078-28-3,38979-86-1) + terephthalic acid (100-21-0)

Guidance literature:

With iodine; In tetrahydrofuran; (N2), reaction for 20 min; IR, NMR;

DOI:10.1016/S0277-5387(00)83759-6

Reference yield: 65.0%

((η5-C5H5)(CO)2FeC(SCH2Ph)SFe(η5-C5H5)(CO)2)Br + tetra-(n-butyl)ammonium iodide (311-28-4) → dicarbonylcyclopentadienyliodoiron(II) (12078-28-3,38979-86-1) + (η5-C5H5)(CO)2FeC(S)SCH2Ph

Guidance literature:

In acetone; under pure N2; crude cationic complex in acetone treated with excess of NBu4I under reflux for 4 h; evapn.,; chromy. (alumina, light petroleum/CH2Cl2 (3/1)), Fe(C5H5)(CO)2I in second fraction, dithiocarboxylate complex from first fraction was recrystallized from n-pentane at -20 ° C,;

DOI:10.1016/0022-328X(88)80532-1

upstream raw materials:

tetrafluoroboric acid diethyl ether

lithium iodide

diiodomethane

cyclopentadienyl iron(II) dicarbonyl dimer

Downstream raw materials:

cyclopentadienyl iron(II) dicarbonyl dimer

{Mn(CO)4(t-BuNC)}2

Tetraisopropoxysilan

triisopropoxysilane

Refernces

• 1、 Friedrich, Holger B.,Moss, John R.. "Reaction Studies on Heterodinuclear Alkanediyl Complexes: Some Examples of Metalloselectivity". . p. 2863 - 2870. Retrieved 1993.
• 2、 Clarkson, L. M.,Norman, N. C.,Farrugia, L. J.. "Indium monohalide insertion reactions into metal-metal bonds. Crystal structure of 2>". . p. C10 - C15. Retrieved 1990.
• 3、 Song, Li-Cheng,Chen, Wei,Feng, Li. "Two heterodinuclear NiFe-based sulfenate complexes mimicking an S-oxygenated intermediate of an O2-tolerant [NiFe]-H2ase: Synthesis, structures, and reactivity". . p. 14015 - 14023. Retrieved 2020.
• 4、 Kumar, Rajesh,Manning, A. R.,Murray, Paul T.. "THE REACTIONS OF 4-n(CNMe)n> (n=0-4) COMPLEXES WITH HALOGENS AND MERCURY(II) SALTS". . p. 53 - 66. Retrieved 1987.
• 5、 Rong, Bingying,Zhong, Wei,Gu, Erxing,Long, Li,Song, Lijuan,Liu, Xiaoming. "Probing the electron transfer mechanism of the half-sandwich iron(II)-carbonyl complexes and their catalysis on proton reduction". . p. 27 - 35. Retrieved 2018.
• 6、 El-Tarhuni, Sarah,Ho, Monica,Kawser, Mohammed H.,Shi, Saiqin,Whiteley, Mark W.. "Synthesis and solvent induced halide exchange of the electron rich, half sandwich complexes [FeI(dppe)Cp] and [MoX(dppe)(η7-C 7H7)] (X = Br, Cl; Dppe = Ph2PCH 2CH2PPh2)". . p. 30 - 36. Retrieved 2014.
• 7、 Schumann, Hans,Speis, Martin,Bosman, W. P.,Smits, J. M. M.,Beurskens, Paul T.. "Monosubstituted nitrogen donors as ligands in cyclopentadienyliron complexes: synthesis, reactivity, ligand properties, and crystal structure of SbF6". . p. 165 - 182. Retrieved 1991.
• 8、 Donegan, Pacelli,Manning, A.R.. "Reactions of tin(IV) halides with (n=1 or 2)". . p. 115 - 128. Retrieved 1987.
• 9、 Hubbard, John L.,McVicar, William K.. "Facile conversion of (η5-C5R5)M(CO)2 - halide complexes to halomethyl, alkoxymethyl, and cyanomethyl derivatives (R = H, CH3; M = Fe, Ru; halide = Cl, Br, I)". . p. 369 - 378. Retrieved 1992.