1,1'-(4,4'-(4-bromophenylazanediyl)bis(4,1-phenylene))dihexan-1-one

Base Information

• Chemical Name: 1,1'-(4,4'-(4-bromophenylazanediyl)bis(4,1-phenylene))dihexan-1-one
• CAS No.: 1361113-09-8
• Molecular Formula: C₃₀H₃₄BrNO₂
• Molecular Weight: 520.509
• Mol file: 1361113-09-8.mol

Synonyms:1,1'-(4,4'-(4-bromophenylazanediyl)bis(4,1-phenylene))dihexan-1-one

Chemical Property of 1,1'-(4,4'-(4-bromophenylazanediyl)bis(4,1-phenylene))dihexan-1-one

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1,1'-(4,4'-(4-bromophenylazanediyl)bis(4,1-phenylene))dihexan-1-one

There total 2 articles about 1,1'-(4,4'-(4-bromophenylazanediyl)bis(4,1-phenylene))dihexan-1-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

7-bromobenzo[5,6][1,4]thiazolo[2,3,4-kl]phenothiazine (1333316-17-8) + Hexanoyl chloride (142-61-0) → 1,1'-(4,4'-(4-bromophenylazanediyl)bis(4,1-phenylene))dihexan-1-one (1361113-09-8)

Guidance literature:

Hexanoyl chloride; With aluminum (III) chloride; In dichloromethane; at 0 ℃; for 1h; Inert atmosphere;

7-bromobenzo[5,6][1,4]thiazolo[2,3,4-kl]phenothiazine; In dichloromethane; at 60 ℃; for 10h; Inert atmosphere;

DOI:10.1016/j.jphotochem.2011.09.020

Reference yield:

benzo[5,6][1,4]thiazole[2,3,4-kl]phenothiazine → 1,1'-(4,4'-(4-bromophenylazanediyl)bis(4,1-phenylene))dihexan-1-one (1361113-09-8)

Guidance literature:

Multi-step reaction with 2 steps

1.1: bromine / acetic acid / 8 h / Inert atmosphere

2.1: aluminum (III) chloride / dichloromethane / 1 h / 0 °C / Inert atmosphere

2.2: 10 h / 60 °C / Inert atmosphere

With aluminum (III) chloride; bromine; In dichloromethane; acetic acid;

DOI:10.1016/j.jphotochem.2011.09.020

Reference yield: 70.0%

1,1'-(4,4'-(4-bromophenylazanediyl)bis(4,1-phenylene))dihexan-1-one (1361113-09-8) → 4-bromo-N,N-bis(4-hexylphenyl)aniline (1361113-11-2)

Guidance literature:

With hydrazine hydrate; potassium hydroxide; In ethylene glycol; at 195 ℃; for 6h; Inert atmosphere;

DOI:10.1016/j.jphotochem.2011.09.020

upstream raw materials:

7-bromobenzo[5,6][1,4]thiazolo[2,3,4-kl]phenothiazine

Hexanoyl chloride

Downstream raw materials:

2,2'-((((4-bromophenyl)azanediyl)bis(3-hexyl-6,1-phenylene))bis(sulfanediyl))bis(isoindoline-1,3-dione)

4-bromo-N,N-bis(4-hexylphenyl)aniline