5-Methoxybenzene-1,2,4-triyl triacetate

Base Information

• Chemical Name: 5-Methoxybenzene-1,2,4-triyl triacetate
• CAS No.: 38475-42-2
• Molecular Formula: C13H14 O7
• Molecular Weight: 282.25
• NSC Number: 144255
• DSSTox Substance ID: DTXSID20301566
• Nikkaji Number: J2.070.543D
• Wikidata: Q82045668
• Mol file: 38475-42-2.mol

Synonyms:38475-42-2;5-methoxybenzene-1,2,4-triyl triacetate;NSC144255;SCHEMBL21723164;DTXSID20301566;NSC-144255

Chemical Property of 5-Methoxybenzene-1,2,4-triyl triacetate

Chemical Property:

• Vapor Pressure: 7.86E-06mmHg at 25°C
• Boiling Point: 375.3°Cat760mmHg
• Flash Point: 165.1°C
• Density: 1.247g/cm³
• XLogP3: 1.1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 7
• Rotatable Bond Count: 7
• Exact Mass: 282.07395278
• Heavy Atom Count: 20
• Complexity: 379

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: CC(=O)OC1=CC(=C(C=C1OC)OC(=O)C)OC(=O)C

Technology Process of 5-Methoxybenzene-1,2,4-triyl triacetate

There total 6 articles about 5-Methoxybenzene-1,2,4-triyl triacetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.0%

2-methoxy-1,4-benzoquinone (2880-58-2) + acetic anhydride (108-24-7) → 2-methoxy-4,5-di-acetoxyphenyl acetate (38475-42-2)

Guidance literature:

With bismuth(lll) trifluoromethanesulfonate; In acetonitrile; at 20 ℃; for 1.16667h;

DOI:10.1016/j.tetlet.2004.06.032

Reference yield:

sulfuric acid (7664-93-9) + 2-methoxy-1,4-benzoquinone (2880-58-2) + acetic anhydride (108-24-7) → 2-methoxy-4,5-di-acetoxyphenyl acetate (38475-42-2)

Guidance literature:

Reference yield:

2-hydroxy-5-methoxycyclohexa-2,5-diene-1,4-dione (5691-70-3) + acetic anhydride (108-24-7) → 2-methoxy-4,5-di-acetoxyphenyl acetate (38475-42-2)

Guidance literature:

With triethylamine; zinc;

DOI:10.1021/ja01125a048

upstream raw materials:

2-hydroxy-5-methoxycyclohexa-2,5-diene-1,4-dione

acetic anhydride

2-methoxy-1,4-benzoquinone

sulfuric acid

Downstream raw materials:

1,2,4,5-tetramethoxybenzene