3-(5-O-tert-butyldiphenylsilyl-2,3-O-isopropylidene-β-D-ribofuranosyl)prop-1-ene

Base Information

Chemical Name:3-(5-O-tert-butyldiphenylsilyl-2,3-O-isopropylidene-β-D-ribofuranosyl)prop-1-ene
CAS No.:82921-68-4
Molecular Formula:C₂₇H₃₆O₄Si
Molecular Weight:452.666
Hs Code.:

Synonyms:3-(5-O-tert-butyldiphenylsilyl-2,3-O-isopropylidene-β-D-ribofuranosyl)prop-1-ene

Suppliers and Price of 3-(5-O-tert-butyldiphenylsilyl-2,3-O-isopropylidene-β-D-ribofuranosyl)prop-1-ene

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 3-(5-O-tert-butyldiphenylsilyl-2,3-O-isopropylidene-β-D-ribofuranosyl)prop-1-ene

Chemical Property:

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Technology Process of 3-(5-O-tert-butyldiphenylsilyl-2,3-O-isopropylidene-β-D-ribofuranosyl)prop-1-ene

There total 3 articles about 3-(5-O-tert-butyldiphenylsilyl-2,3-O-isopropylidene-β-D-ribofuranosyl)prop-1-ene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 55.0%

: 82921-64-0
1-O-acetyl-5-O-tert-butyldiphenylsilyl-2,3-O-isopropylidene-β-D-ribofuranose

: 762-72-1
allyl-trimethyl-silane

: 82950-51-4
3-(5-O-tert-butyldiphenylsilyl-2,3-O-isopropylidene-α-D-ribofuranosyl)prop-1-ene

: 82921-68-4
3-(5-O-tert-butyldiphenylsilyl-2,3-O-isopropylidene-β-D-ribofuranosyl)prop-1-ene

Guidance literature:: With zinc dibromide; In nitromethane; at 20 ℃; for 1h; optical yield given as %de; stereoselective reaction;
DOI:10.1055/s-0029-1216794

Reference yield:

: 62410-12-2
1,5-di-O-acetyl-2,3-O-isopropylidene-β-D-ribofuranose

: 82921-68-4
3-(5-O-tert-butyldiphenylsilyl-2,3-O-isopropylidene-β-D-ribofuranosyl)prop-1-ene

Guidance literature:: Multi-step reaction with 3 steps

1.1: zinc dibromide / nitromethane

2.1: sodium methylate / methanol / 1.25 h / 20 °C

2.2: IR₁₂₀ (H⁺) Amberlite resin

3.1: pyridine / 12 h / 0 - 20 °C

With pyridine; sodium methylate; zinc dibromide; In methanol; nitromethane;
DOI:10.1055/s-0030-1260200

Reference yield:

: 174392-13-3
3-(5-O-acetyl-2,3-O-isopropylidene-β-D-ribofuranosyl)prop-1-ene

: 82921-68-4
3-(5-O-tert-butyldiphenylsilyl-2,3-O-isopropylidene-β-D-ribofuranosyl)prop-1-ene

Guidance literature:: Multi-step reaction with 2 steps

1.1: sodium methylate / methanol / 1.25 h / 20 °C

1.2: IR₁₂₀ (H⁺) Amberlite resin

2.1: pyridine / 12 h / 0 - 20 °C

With pyridine; sodium methylate; In methanol;
DOI:10.1055/s-0030-1260200