(4-flourophenyl)methylene-1,1-dihydroperoxide

Base Information

• Chemical Name: (4-flourophenyl)methylene-1,1-dihydroperoxide
• CAS No.: 1357193-86-2
• Molecular Formula: C₇H₇FO₄
• Molecular Weight: 174.129
• Mol file: 1357193-86-2.mol

Synonyms:(4-flourophenyl)methylene-1,1-dihydroperoxide

Chemical Property of (4-flourophenyl)methylene-1,1-dihydroperoxide

Chemical Property:

Purity/Quality:

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Technology Process of (4-flourophenyl)methylene-1,1-dihydroperoxide

There total 1 articles about (4-flourophenyl)methylene-1,1-dihydroperoxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

4-fluorobenzaldehyde (459-57-4) → (4-flourophenyl)methylene-1,1-dihydroperoxide (1357193-86-2)

Guidance literature:

With aluminium(III) chloride hexahydrate; dihydrogen peroxide; In water; acetonitrile; at 20 ℃; for 11h;

DOI:10.1007/BF03246556

Reference yield: 92.0%

triethylsilyl chloride (994-30-9) + (4-flourophenyl)methylene-1,1-dihydroperoxide (1357193-86-2) → 1-(bis(triethylsilylperoxy)methyl)-4-fluorobenzene

Guidance literature:

With 2,6-dimethylpyridine; In dichloromethane; at 0 ℃; for 2h; Inert atmosphere;

DOI:10.1021/acs.joc.0c02180

Reference yield:

(4-flourophenyl)methylene-1,1-dihydroperoxide (1357193-86-2) + 4-fluorobenzaldehyde (459-57-4) → 3,6-Bis-(4-fluoro-phenyl)-[1,2,4,5]tetroxane (75895-51-1)

Guidance literature:

With tetrafluoroboric acid diethyl ether; In acetonitrile; at 20 ℃;

DOI:10.1016/j.bmcl.2009.01.103

upstream raw materials:

4-fluorobenzaldehyde

Downstream raw materials:

3,6-Bis-(4-fluoro-phenyl)-[1,2,4,5]tetroxane