(2R,4aR,6S,7R,8R,8aS)-6-((2R,3S,4R,5R,6R)-6-Azido-4,5-dihydroxy-2-hydroxymethyl-tetrahydro-pyran-3-yloxy)-2-(4-methoxy-phenyl)-hexahydro-pyrano[3,2-d][1,3]dioxine-7,8-diol

Base Information

Chemical Name:(2R,4aR,6S,7R,8R,8aS)-6-((2R,3S,4R,5R,6R)-6-Azido-4,5-dihydroxy-2-hydroxymethyl-tetrahydro-pyran-3-yloxy)-2-(4-methoxy-phenyl)-hexahydro-pyrano[3,2-d][1,3]dioxine-7,8-diol
CAS No.:908845-56-7
Molecular Formula:C₂₀H₂₇N₃O₁₁
Molecular Weight:485.448
Hs Code.:

(2R,4aR,6S,7R,8R,8aS)-6-((2R,3S,4R,5R,6R)-6-Azido-4,5-dihydroxy-2-hydroxymethyl-tetrahydro-pyran-3-yloxy)-2-(4-methoxy-phenyl)-hexahydro-pyrano[3,2-d][1,3]dioxine-7,8-diol

Synonyms:(2R,4aR,6S,7R,8R,8aS)-6-((2R,3S,4R,5R,6R)-6-Azido-4,5-dihydroxy-2-hydroxymethyl-tetrahydro-pyran-3-yloxy)-2-(4-methoxy-phenyl)-hexahydro-pyrano[3,2-d][1,3]dioxine-7,8-diol

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Chemical Property of (2R,4aR,6S,7R,8R,8aS)-6-((2R,3S,4R,5R,6R)-6-Azido-4,5-dihydroxy-2-hydroxymethyl-tetrahydro-pyran-3-yloxy)-2-(4-methoxy-phenyl)-hexahydro-pyrano[3,2-d][1,3]dioxine-7,8-diol

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Technology Process of (2R,4aR,6S,7R,8R,8aS)-6-((2R,3S,4R,5R,6R)-6-Azido-4,5-dihydroxy-2-hydroxymethyl-tetrahydro-pyran-3-yloxy)-2-(4-methoxy-phenyl)-hexahydro-pyrano[3,2-d][1,3]dioxine-7,8-diol

There total 3 articles about (2R,4aR,6S,7R,8R,8aS)-6-((2R,3S,4R,5R,6R)-6-Azido-4,5-dihydroxy-2-hydroxymethyl-tetrahydro-pyran-3-yloxy)-2-(4-methoxy-phenyl)-hexahydro-pyrano[3,2-d][1,3]dioxine-7,8-diol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 69194-62-3
4-O-(β-D-glucopyranosyl)-β-D-glucopyranosyl azide

: 2186-92-7
p-Anisaldehyde dimethyl acetal

: 908845-56-7
(2R,4aR,6S,7R,8R,8aS)-6-((2R,3S,4R,5R,6R)-6-Azido-4,5-dihydroxy-2-hydroxymethyl-tetrahydro-pyran-3-yloxy)-2-(4-methoxy-phenyl)-hexahydro-pyrano[3,2-d][1,3]dioxine-7,8-diol

Guidance literature:: With Amberlyst 15; In N,N-dimethyl-formamide; at 50 ℃;
DOI:10.1016/j.tetlet.2006.06.001

Reference yield:

: 20764-63-0
β-cellobioseoctaacetate

: 908845-56-7
(2R,4aR,6S,7R,8R,8aS)-6-((2R,3S,4R,5R,6R)-6-Azido-4,5-dihydroxy-2-hydroxymethyl-tetrahydro-pyran-3-yloxy)-2-(4-methoxy-phenyl)-hexahydro-pyrano[3,2-d][1,3]dioxine-7,8-diol

Guidance literature:: Multi-step reaction with 3 steps

1: TMSN₃; SnCl₄ / CH₂Cl₂

2: NaOMe / methanol

3: Amberlyst 15 / dimethylformamide / 50 °C

With Amberlyst 15; trimethylsilylazide; sodium methylate; tin(IV) chloride; In methanol; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1016/j.tetlet.2006.06.001

Reference yield:

: 33012-50-9
2,2',3,3',4',6,6'-hepta-O-acetyl-β-D-cellobiosyl azide

: 908845-56-7
(2R,4aR,6S,7R,8R,8aS)-6-((2R,3S,4R,5R,6R)-6-Azido-4,5-dihydroxy-2-hydroxymethyl-tetrahydro-pyran-3-yloxy)-2-(4-methoxy-phenyl)-hexahydro-pyrano[3,2-d][1,3]dioxine-7,8-diol

Guidance literature:: Multi-step reaction with 2 steps

1: NaOMe / methanol

2: Amberlyst 15 / dimethylformamide / 50 °C

With Amberlyst 15; sodium methylate; In methanol; N,N-dimethyl-formamide;
DOI:10.1016/j.tetlet.2006.06.001