20764-63-0Relevant academic research and scientific papers
Synthesis of aryl glycosides as vir gene inducers of Agrobacterium tumefaciens
Delay,Cizeau,Delmotte
, p. 179 - 188 (2007/10/02)
Aryl β-glycopyranosides have been synthesized by coupling syringaldehyde (3-methoxyvanillin) with L-fucose, D-galactose, and maltose; acetosyringone (4-hydroxy-3,5-dimethoxyacetophenone) with L-fucose and maltose; acetovanillone (4-hydroxy-3-methoxyacetophenone) with L-fucose; and syringic acid (4-hydroxy-3,5-dimethoxybenzoic acid) with D-galactose. The procedure using peracetylated glycosyl halides and sodium phenolates in aqueous acetone afforded the acetylated β-glycosides, which were deacetylated. Aryl β-glycopyranosides have been synthesized by coupling syringaldehyde (3-methoxyvanillin) with L-fucose, D-galactose, and maltose; acetosyringone (4-hydroxy-3,5-dimethoxyacetophenone) with L-fucose and maltose; acetovanillone (4-hydroxy-3-methoxyacetophenone) with L-fucose; and syringic acid (4-hydroxy-3,5-dimethoxybenzoic acid) with D-galactose. The procedure using peracetylated glycosyl halides and sodium phenolates in aqueous acetone afforded the acetylated β-glycosides, which were deacetylated.
NOVEL HIGHLY STEREOSPECIFIC METHOD OF 1,2-CIS-GLYCOSYLATION. SYNTHESIS OF α-D-GLUCOSYL-D-GLUCOSES
Kochetkov, Nikolay K.,Klimov, Evgeny M.,Malysheva, Nelly N.
, p. 5459 - 5462 (2007/10/02)
Triphenylmethylium perchlorate-catalysed glycosylation of 2-, 3-, 4-, and 6-O-trityl-D-glucose derivatives with β-D-glucopyranosyl thiocyanates bearing a nonparticipating substituent at O-2 affords stereospecific derivatives of α-D-glucosyl-D-glucose
