methyl (E)-2-(phenylseleno)-3-(p-tolylsulfonyl)-2-propenoate

Base Information

• Chemical Name: methyl (E)-2-(phenylseleno)-3-(p-tolylsulfonyl)-2-propenoate
• CAS No.: 86409-88-3
• Molecular Formula: C₁₇H₁₆O₄SSe
• Molecular Weight: 395.338
• Mol file: 86409-88-3.mol

Synonyms:methyl (E)-2-(phenylseleno)-3-(p-tolylsulfonyl)-2-propenoate

Chemical Property of methyl (E)-2-(phenylseleno)-3-(p-tolylsulfonyl)-2-propenoate

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of methyl (E)-2-(phenylseleno)-3-(p-tolylsulfonyl)-2-propenoate

There total 1 articles about methyl (E)-2-(phenylseleno)-3-(p-tolylsulfonyl)-2-propenoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

p-tolyl benzeneselenosulfonate (68819-94-3) + propynoic acid methyl ester (922-67-8) → methyl (E)-2-(phenylseleno)-3-(p-tolylsulfonyl)-2-propenoate (86409-88-3)

Guidance literature:

With 2,2'-azobis(isobutyronitrile); In chloroform; for 24h; Heating;

DOI:10.1021/jo00166a030

Reference yield:

methyl (E)-2-(phenylseleno)-3-(p-tolylsulfonyl)-2-propenoate (86409-88-3) → C17H16O5SSe (86409-93-0)

Guidance literature:

With 3-chloro-benzenecarboperoxoic acid; In chloroform; for 0.166667h; Ambient temperature;

DOI:10.1021/jo00166a030

Reference yield:

methyl (E)-2-(phenylseleno)-3-(p-tolylsulfonyl)-2-propenoate (86409-88-3) → 3-Chloro-benzoic acid (Z)-2-methoxycarbonyl-1-(toluene-4-sulfonyl)-vinyl ester (86409-94-1)

Guidance literature:

Multi-step reaction with 2 steps

1: m-chloroperbenzoic acid / CHCl₃ / 0.17 h / Ambient temperature

2: 38 mg / CHCl₃ / 1 h / Heating

With 3-chloro-benzenecarboperoxoic acid; In chloroform;

DOI:10.1021/jo00166a030

upstream raw materials:

p-tolyl benzeneselenosulfonate

propynoic acid methyl ester

Downstream raw materials:

C₁₇H₁₆O₅SSe

3-Chloro-benzoic acid (Z)-2-methoxycarbonyl-1-(toluene-4-sulfonyl)-vinyl ester