C₁₀H₁₆O₄S*C₇H₉NOS

Base Information

• Chemical Name: C₁₀H₁₆O₄S*C₇H₉NOS
• CAS No.: 7044-59-9
• Molecular Formula: C₇H₉NOS*C₁₀H₁₆O₄S
• Molecular Weight: 387.521
• Mol file: 7044-59-9.mol

Synonyms:C₁₀H₁₆O₄S*C₇H₉NOS

Chemical Property of C₁₀H₁₆O₄S*C₇H₉NOS

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₁₀H₁₆O₄S*C₇H₉NOS

There total 3 articles about C₁₀H₁₆O₄S*C₇H₉NOS which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 38.0%

(1S)-10-camphorsulfonic acid (3144-16-9,61380-66-3) + S-methyl-S-phenylsulfoximine (4381-25-3) → C10H16O4S*C7H9NOS (7044-59-9)

Guidance literature:

In acetone; Inert atmosphere; Schlenk technique;

DOI:10.1002/chem.201504724

Reference yield:

methyl-phenyl-thioether (100-68-5) → C10H16O4S*C7H9NOS (7044-59-9)

Guidance literature:

Multi-step reaction with 3 steps

1: sodium periodate / water / 3.5 h / 0 - 20 °C / Inert atmosphere; Schlenk technique

2: sodium azide; sulfuric acid / tetrahydrofuran / 20.5 h / 0 °C / Inert atmosphere; Reflux; Schlenk technique

3: acetone / Inert atmosphere; Schlenk technique

With sodium periodate; sodium azide; sulfuric acid; In tetrahydrofuran; water; acetone;

DOI:10.1002/chem.201504724

Reference yield:

racemic methyl phenyl sulfoxide (1193-82-4) → C10H16O4S*C7H9NOS (7044-59-9)

Guidance literature:

Multi-step reaction with 2 steps

1: sodium azide; sulfuric acid / tetrahydrofuran / 20.5 h / 0 °C / Inert atmosphere; Reflux; Schlenk technique

2: acetone / Inert atmosphere; Schlenk technique

With sodium azide; sulfuric acid; In tetrahydrofuran; acetone;

DOI:10.1002/chem.201504724

upstream raw materials:

methyl-phenyl-thioether

(1S)-10-camphorsulfonic acid

S-methyl-S-phenylsulfoximine

racemic methyl phenyl sulfoxide

Downstream raw materials:

N,S-dimethyl-S-phenylsulfoximine

(S)-S-methyl-S-phenylsulfoximine

Refernces

• 1、 Feichtner, Kai-Stephan,Englert, Simon,Gessner, Viktoria H.. "Preparation and Isolation of a Chiral Methandiide and Its Application as Cooperative Ligand in Bond Activation". . p. 506 - 510. Retrieved 2016/01/15.