Torularhodinaldehyde

Base Information

Chemical Name:Torularhodinaldehyde
CAS No.:5999-29-1
Molecular Formula:C₄₀H₅₂O
Molecular Weight:548.852
Hs Code.:
UNII:11EXT0X0KN
Metabolomics Workbench ID:112406
Nikkaji Number:J2.522.398E
Wikidata:Q77381202

Synonyms:Torularhodinaldehyde;11EXT0X0KN;5999-29-1;(2E,4E,6E,8E,10E,12E,14E,16E,18E,20E,22E,24E)-2,6,10,14,19,23-Hexamethyl-25-(2,6,6-trimethyl-1-cyclohexen-1-yl)-2,4,6,8,10,12,14,16,18,20,22,24-pentacosadodecaenal;2,4,6,8,10,12,14,16,18,20,22,24-Pentacosadodecaenal, 2,6,10,14,19,23-hexamethyl-25-(2,6,6-trimethyl-1-cyclohexen-1-yl)-, (2E,4E,6E,8E,10E,12E,14E,16E,18E,20E,22E,24E)-;UNII-11EXT0X0KN;SCHEMBL2838479;CHEBI:203830;gamma-Carotenal, 3',4'-didehydro-;gamma-Caroten-16'-al, 3',4'-didehydro-;.GAMMA.-CAROTENAL, 3',4'-DIDEHYDRO-;beta,psi-Caroten-16'-al, 3',4'-didehydro-;.GAMMA.-CAROTEN-16'-AL, 3',4'-DIDEHYDRO-;.BETA.,.PSI.-CAROTEN-16'-AL, 3',4'-DIDEHYDRO-;(2E,4E,6E,8E,10E,12E,14E,16E,18E,20E,22E,24E)-2,6,10,14,19,23-hexamethyl-25-(2,6,6-trimethylcyclohexen-1-yl)pentacosa-2,4,6,8,10,12,14,16,18,20,22,24-dodecaenal

Suppliers and Price of Torularhodinaldehyde

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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Total 0 raw suppliers

Chemical Property of Torularhodinaldehyde

Chemical Property:

XLogP3:13.2
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:13
Exact Mass:548.401816278
Heavy Atom Count:41
Complexity:1280

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CC1=C(C(CCC1)(C)C)C=CC(=CC=CC(=CC=CC=C(C)C=CC=C(C)C=CC=C(C)C=CC=C(C)C=O)C)C
Isomeric SMILES:CC1=C(C(CCC1)(C)C)/C=C/C(=C/C=C/C(=C/C=C/C=C(\C)/C=C/C=C(\C)/C=C/C=C(\C)/C=C/C=C(\C)/C=O)/C)/C

Technology Process of Torularhodinaldehyde

There total 12 articles about Torularhodinaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 53.0%

: C₂₈H₃₂BrO₂P

: 5056-12-2
(2E,4E,6E,8E,10E,12Z,14E,16E,18E,20E)-2,6,10,15,19-Pentamethyl-21-(2,6,6-trimethyl-cyclohex-1-enyl)-henicosa-2,4,6,8,10,12,14,16,18,20-decaenal

: 5999-29-1
all-E-3',4'-didehydro-β,ψ-caroten-16'-al

Guidance literature:: C₂₈H₃₂BrO₂P; (2E,4E,6E,8E,10E,12Z,14E,16E,18E,20E)-2,6,10,15,19-Pentamethyl-21-(2,6,6-trimethyl-cyclohex-1-enyl)-henicosa-2,4,6,8,10,12,14,16,18,20-decaenal; With sodium methylate; In methanol; for 24h; Reflux;

With toluene-4-sulfonic acid; In acetone; for 2h;
DOI:10.1016/j.tet.2012.10.041

Reference yield:

: 3950-23-0
8-acetoxy-2,6-dimethyl-octa-2,4,6-trien-1-al

: 5999-29-1
all-E-3',4'-didehydro-β,ψ-caroten-16'-al

Guidance literature:: Multi-step reaction with 4 steps

1: aq. NaOH / methanol

2: PBr₃ / dimethylformamide; CH₂Cl₂

3: CH₂Cl₂

4: (i) HC(OEt)3, TsOH, EtOH, (ii) NaOEt, CH₂Cl₂

With sodium hydroxide; phosphorus tribromide; In methanol; dichloromethane; N,N-dimethyl-formamide;

Reference yield:

: 62073-42-1
(2E,4E,6E)-8-hydroxy-2,6-dimethyl-octa-2,4,6-trienal

: 5999-29-1
all-E-3',4'-didehydro-β,ψ-caroten-16'-al

Guidance literature:: Multi-step reaction with 3 steps

1: PBr₃ / dimethylformamide; CH₂Cl₂

2: CH₂Cl₂

3: (i) HC(OEt)3, TsOH, EtOH, (ii) NaOEt, CH₂Cl₂

With phosphorus tribromide; In dichloromethane; N,N-dimethyl-formamide;