C₇₇H₁₂₉NO₁₂Si₄

Base Information

Chemical Name:C₇₇H₁₂₉NO₁₂Si₄
CAS No.:215876-23-6
Molecular Formula:C₇₇H₁₂₉NO₁₂Si₄
Molecular Weight:1373.21
Hs Code.:

C<sub>77</sub>H<sub>129</sub>NO<sub>12</sub>Si<sub>4</sub>

Synonyms:C₇₇H₁₂₉NO₁₂Si₄

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of C₇₇H₁₂₉NO₁₂Si₄

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Technology Process of C₇₇H₁₂₉NO₁₂Si₄

There total 53 articles about C₇₇H₁₂₉NO₁₂Si₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 994-30-9
triethylsilyl chloride

: 215876-22-5
C₇₁H₁₁₅NO₁₂Si₃

: 215876-23-6
C₇₇H₁₂₉NO₁₂Si₄

Guidance literature:: With 1H-imidazole; In acetonitrile;
DOI:10.1002/(SICI)1521-3773(19980918)37:17<2354::AID-ANIE2354>3.0.CO;2-9

Reference yield:

: 215876-11-2
(2R,4S,6S)-2-Benzyloxymethyl-6-hydroxymethyl-tetrahydro-pyran-4-ol

: 215876-23-6
C₇₇H₁₂₉NO₁₂Si₄

Guidance literature:: Multi-step reaction with 10 steps

1.1: imidazole; DMAP / CH₂Cl₂

2.1: H₂; AcOH / 10 percent Pd/C / ethyl acetate / 760 Torr

3.1: 85 percent / (COCl)2; DMSO; Et₃N / CH₂Cl₂ / -78 - -50 °C

4.1: n-BuLi / tetrahydrofuran / -78 °C

4.2: tetrahydrofuran / -78 - -50 °C

5.1: DMAP / CH₂Cl₂

6.1: 64 percent / Mg; HgCl₂; EtOH

7.1: 75 percent / TBAF / tetrahydrofuran / -15 °C

8.1: 95 percent / 2,6-lutidine / CH₂Cl₂ / -10 °C

9.1: n-BuLi / tetrahydrofuran / -78 °C

9.2: 87 percent / HMPA / tetrahydrofuran / -78 °C

10.1: 85 percent / imidazole / acetonitrile

With 1H-imidazole; 2,6-dimethylpyridine; dmap; n-butyllithium; oxalyl dichloride; ethanol; tetrabutyl ammonium fluoride; hydrogen; magnesium; acetic acid; dimethyl sulfoxide; triethylamine; mercury dichloride; palladium on activated charcoal; In tetrahydrofuran; dichloromethane; ethyl acetate; acetonitrile; 1.1: silylation / 2.1: Hydrogenolysis / 3.1: Oxidation / 4.1: Metallation / 4.2: Substitution / 5.1: Acetylation / 6.1: Deacetylation / 7.1: desilylation / 8.1: Esterification / 9.1: Metallation / 9.2: Substitution / 10.1: Ring cleavage;
DOI:10.1021/ja990860j

Reference yield:

: 247146-46-9
2-benzyloxymethyl-4-(tert-butyl-dimethyl-silanyloxy)-6-(tert-butyl-dimethyl-silanyloxymethyl)-tetrahydro-pyran

: 215876-23-6
C₇₇H₁₂₉NO₁₂Si₄

Guidance literature:: Multi-step reaction with 9 steps

1.1: H₂; AcOH / 10 percent Pd/C / ethyl acetate / 760 Torr

2.1: 85 percent / (COCl)2; DMSO; Et₃N / CH₂Cl₂ / -78 - -50 °C

3.1: n-BuLi / tetrahydrofuran / -78 °C

3.2: tetrahydrofuran / -78 - -50 °C

4.1: DMAP / CH₂Cl₂

5.1: 64 percent / Mg; HgCl₂; EtOH

6.1: 75 percent / TBAF / tetrahydrofuran / -15 °C

7.1: 95 percent / 2,6-lutidine / CH₂Cl₂ / -10 °C

8.1: n-BuLi / tetrahydrofuran / -78 °C

8.2: 87 percent / HMPA / tetrahydrofuran / -78 °C

9.1: 85 percent / imidazole / acetonitrile

With 1H-imidazole; 2,6-dimethylpyridine; dmap; n-butyllithium; oxalyl dichloride; ethanol; tetrabutyl ammonium fluoride; hydrogen; magnesium; acetic acid; dimethyl sulfoxide; triethylamine; mercury dichloride; palladium on activated charcoal; In tetrahydrofuran; dichloromethane; ethyl acetate; acetonitrile; 1.1: Hydrogenolysis / 2.1: Oxidation / 3.1: Metallation / 3.2: Substitution / 4.1: Acetylation / 5.1: Deacetylation / 6.1: desilylation / 7.1: Esterification / 8.1: Metallation / 8.2: Substitution / 9.1: Ring cleavage;
DOI:10.1021/ja990860j