C₅₁H₇₈O₁₁Si

Base Information

Chemical Name:C₅₁H₇₈O₁₁Si
CAS No.:1032880-22-0
Molecular Formula:C₅₁H₇₈O₁₁Si
Molecular Weight:895.259
Hs Code.:

C<sub>51</sub>H<sub>78</sub>O<sub>11</sub>Si

Synonyms:C₅₁H₇₈O₁₁Si

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Chemical Property of C₅₁H₇₈O₁₁Si

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Technology Process of C₅₁H₇₈O₁₁Si

There total 18 articles about C₅₁H₇₈O₁₁Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.0%

: 1032880-20-8
C₅₁H₇₆O₁₁Si

: 1032880-22-0
C₅₁H₇₈O₁₁Si

: 1032880-24-2
C₅₁H₇₈O₁₁Si

Guidance literature:: With acetic acid; tetramethylammonium triacetoxyborohydride; In acetonitrile; at -30 ℃; for 12h; Overall yield = 91 %;
DOI:10.3987/COM-12-S(N)54

Reference yield:

: 1032880-15-1
C₃₆H₅₂O₇Si

: 1032880-22-0
C₅₁H₇₈O₁₁Si

Guidance literature:: Multi-step reaction with 3 steps

1: dimethyl sulfoxide; triethylamine; sulfur trioxide pyridine complex / dichloromethane / 2 h / 0 °C

2: boron trifluoride diethyl etherate / dichloromethane / 1 h / -78 °C

3: tetramethylammonium triacetoxyborohydride; acetic acid / acetonitrile / 12 h / -30 °C

With boron trifluoride diethyl etherate; sulfur trioxide pyridine complex; acetic acid; dimethyl sulfoxide; triethylamine; tetramethylammonium triacetoxyborohydride; In dichloromethane; acetonitrile; 2: |Mukaiyama Aldol Addition;
DOI:10.3987/COM-12-S(N)54

Reference yield:

: 101331-92-4
4-O-(tert-butyldiphenylsilyl)-2,3-O-isopropylidene-L-threose

: 1032880-22-0
C₅₁H₇₈O₁₁Si

Guidance literature:: Multi-step reaction with 13 steps

1.1: (-)-B-methoxydiisopinocamphenylborane / diethyl ether / 1 h / 0 - 20 °C

1.2: 3 h / -78 °C

2.1: sodium hydride / tetrahydrofuran / 1 h / -10 - 20 °C

2.2: 12 h / 20 °C

3.1: 9-bora-bicyclo[3.3.1]nonane / tetrahydrofuran / 5 h / 0 - 20 °C

3.2: 2 h / Reflux

4.1: dimethyl sulfoxide; triethylamine; sulfur trioxide pyridine complex / dichloromethane / 2 h / -10 °C

5.1: 2-methyl-but-2-ene; sodium dihydrogenphosphate; sodium chlorite / water; tert-butyl alcohol / 1 h / -10 - 20 °C

6.1: toluene-4-sulfonic acid / dichloromethane / 3 h / 0 - 20 °C

7.1: pyridine; dmap / dichloromethane / 20 °C

8.1: tetrahydrofuran / 1 h / -78 °C

8.2: 0.03 h / -78 °C / Molecular sieve

9.1: tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride / toluene / 8 h / 20 °C

10.1: 2,3-dicyano-5,6-dichloro-p-benzoquinone / dichloromethane / 1.5 h / 20 °C

11.1: dimethyl sulfoxide; triethylamine; sulfur trioxide pyridine complex / dichloromethane / 2 h / 0 °C

12.1: boron trifluoride diethyl etherate / dichloromethane / 1 h / -78 °C

13.1: tetramethylammonium triacetoxyborohydride; acetic acid / acetonitrile / 12 h / -30 °C

With pyridine; tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride; dmap; sodium chlorite; sodium dihydrogenphosphate; 2-methyl-but-2-ene; (-)-B-methoxydiisopinocamphenylborane; boron trifluoride diethyl etherate; sulfur trioxide pyridine complex; sodium hydride; toluene-4-sulfonic acid; acetic acid; dimethyl sulfoxide; triethylamine; 9-bora-bicyclo[3.3.1]nonane; 2,3-dicyano-5,6-dichloro-p-benzoquinone; tetramethylammonium triacetoxyborohydride; In tetrahydrofuran; diethyl ether; dichloromethane; water; toluene; acetonitrile; tert-butyl alcohol; 12.1: |Mukaiyama Aldol Addition;
DOI:10.3987/COM-12-S(N)54