1032880-24-2Relevant academic research and scientific papers
Assembly of the southern macrocyclic half of (+)-spirastrellolide a through cyclic acetal tethered ring-closing metathesis and 1,3-anti-mukaiyama-aldol
Tang, Yu,Yang, Jin-Haek,Liu, Jia,Wang, Chao-Chao,Lv, Ming-Can,Wu, Yi-Biao,Yu, Xue-Liang,Ko, Changhong,Hsung, Richard P.
, p. 565 - 598 (2013/08/23)
We describe herein details of our efforts in syntheses of A-ring and BC-ring of (+)-spirastrellolide A. While the former would constitute a facile 12-step synthetic endeavor starting from 1,5-pentanediol, the latter would showcase a cyclic acetal-tethered
Synthesis of the C1-C23 fragment of spirastrellolide A
Yang, Jin-Haek,Liu, Jia,Hsung, Richard P.
supporting information; experimental part, p. 2525 - 2528 (2009/05/27)
(Chemical Equation Presented) Synthesis of the C1-C23 fragment in spirastrellolide A is described, featuring a cyclic acetal-tethered RCM for stereoselective constructions of spiroketal, and a 1,3-anti aldol involving methyl ketone enolate and Mukaiyama c
