diisopropyl azodicarboxylate-triphenylphosphine

Base Information

• Chemical Name: diisopropyl azodicarboxylate-triphenylphosphine
• CAS No.: 86825-70-9
• Molecular Formula: C₂₆H₂₉N₂O₄P
• Molecular Weight: 464.501
• Mol file: 86825-70-9.mol

Synonyms:diisopropyl azodicarboxylate-triphenylphosphine

Chemical Property of diisopropyl azodicarboxylate-triphenylphosphine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of diisopropyl azodicarboxylate-triphenylphosphine

There total 3 articles about diisopropyl azodicarboxylate-triphenylphosphine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

diisopropyl (E)-azodicarboxylate (2446-83-5) + triphenylphosphine (603-35-0) → diisopropyl azodicarboxylate-triphenylphosphine (86825-70-9) + Triphenylphosphine oxide (791-28-6)

Guidance literature:

In toluene; at 0 ℃;

DOI:10.1016/0040-4039(95)02282-1

Reference yield:

di-isopropyl azodicarboxylate (2446-83-5) + triphenylphosphine (603-35-0) → diisopropyl azodicarboxylate-triphenylphosphine (86825-70-9)

Guidance literature:

In dichloromethane; at -20 ℃;

DOI:10.1021/jo982362j

Reference yield:

9-phenyl-9-phosphafluorene (1088-00-2) + di-isopropyl azodicarboxylate (2446-83-5) + triphenylphosphine (603-35-0) → C26H27N2O4P + diisopropyl azodicarboxylate-triphenylphosphine (86825-70-9)

Guidance literature:

In tetrahydrofuran; at 0 ℃; Inert atmosphere;

DOI:10.1016/j.tet.2015.05.099

upstream raw materials:

diisopropyl (E)-azodicarboxylate

triphenylphosphine

di-isopropyl azodicarboxylate

9-phenyl-9-phosphafluorene

Downstream raw materials:

Triphenylphosphine oxide