β-keto α-phenylthio hexyl p-toluene sulfone

Base Information

• Chemical Name: β-keto α-phenylthio hexyl p-toluene sulfone
• CAS No.: 137351-37-2
• Molecular Formula: C₂₁H₂₆O₃S₂
• Molecular Weight: 390.568
• Mol file: 137351-37-2.mol

Synonyms:β-keto α-phenylthio hexyl p-toluene sulfone

Chemical Property of β-keto α-phenylthio hexyl p-toluene sulfone

Chemical Property:

Purity/Quality:

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Technology Process of β-keto α-phenylthio hexyl p-toluene sulfone

There total 2 articles about β-keto α-phenylthio hexyl p-toluene sulfone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 55.0%

1-Chloro-1-phenylsulfanyl-octan-2-one (87143-60-0) + sodium 4-methylbenzenesulfinate (824-79-3) → β-keto α-phenylthio hexyl p-toluene sulfone (137351-37-2)

Guidance literature:

With tetra(n-butyl)ammonium hydrogensulfate; In acetone; benzene; at 60 ℃; for 4h;

DOI:10.1080/00397919108019810

Reference yield:

1-Phenylthiooctan-2-on (71221-50-6) → β-keto α-phenylthio hexyl p-toluene sulfone (137351-37-2)

Guidance literature:

Multi-step reaction with 2 steps

1: N-chloro succinimide / CCl₄ / 2 h / 0 °C

2: 55 percent / tetrabutylammonium hydrogen sulphate / acetone; benzene / 4 h / 60 °C

With N-chloro-succinimide; tetra(n-butyl)ammonium hydrogensulfate; In tetrachloromethane; acetone; benzene;

DOI:10.1080/00397919108019810

upstream raw materials:

1-Chloro-1-phenylsulfanyl-octan-2-one

sodium 4-methylbenzenesulfinate

1-Phenylthiooctan-2-on