1,3-bis(4-iodo-2,6-diisopropylphenyl)-1H-imidazol-3-ium trifluoromethanesulfonate

Base Information

• Chemical Name: 1,3-bis(4-iodo-2,6-diisopropylphenyl)-1H-imidazol-3-ium trifluoromethanesulfonate
• CAS No.: 1259556-09-6
• Molecular Formula: CF₃O₃S*C₂₇H₃₅I₂N₂
• Molecular Weight: 790.468
• Mol file: 1259556-09-6.mol

Synonyms:1,3-bis(4-iodo-2,6-diisopropylphenyl)-1H-imidazol-3-ium trifluoromethanesulfonate

Chemical Property of 1,3-bis(4-iodo-2,6-diisopropylphenyl)-1H-imidazol-3-ium trifluoromethanesulfonate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1,3-bis(4-iodo-2,6-diisopropylphenyl)-1H-imidazol-3-ium trifluoromethanesulfonate

There total 1 articles about 1,3-bis(4-iodo-2,6-diisopropylphenyl)-1H-imidazol-3-ium trifluoromethanesulfonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

Chloromethyl pivalate (18997-19-8) + N,N'-bis(4-iodo-2,6-diisopropylphenyl)1,4-diazabutadiene (934008-46-5) + silver trifluoromethanesulfonate (2923-28-6) → 1,3-bis(4-iodo-2,6-diisopropylphenyl)-1H-imidazol-3-ium trifluoromethanesulfonate (1259556-09-6)

Guidance literature:

In dichloromethane; for 25h; Reflux;

DOI:10.1016/j.jcat.2010.09.004

Reference yield: 85.0%

sodium tetrachloroaurate(III) dihydrate + 1,3-bis(4-iodo-2,6-diisopropylphenyl)-1H-imidazol-3-ium trifluoromethanesulfonate (1259556-09-6) → C27H34AuClI2N2 (1514905-14-6)

Guidance literature:

With 3-Chloropyridine; sodium carbonate;

DOI:10.1021/cs400983y

Reference yield: 80.0%

Triethoxysilane (998-30-1) + 1,3-bis(4-iodo-2,6-diisopropylphenyl)-1H-imidazol-3-ium trifluoromethanesulfonate (1259556-09-6) → 1,3-bis(4-triethoxysilyl-2,6-diisopropylphenyl)-1H-imidazol-3-ium trifluoromethanesulfonate (1259556-12-1)

Guidance literature:

With bis(acetonitrile)(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate; triethylamine; In N,N-dimethyl-formamide; at 80 ℃; for 8h; Inert atmosphere;

DOI:10.1016/j.jcat.2010.09.004

upstream raw materials:

Chloromethyl pivalate

N,N'-bis(4-iodo-2,6-diisopropylphenyl)1,4-diazabutadiene

silver trifluoromethanesulfonate

Downstream raw materials:

1,3-bis(4-triethoxysilyl-2,6-diisopropylphenyl)-1H-imidazol-3-ium trifluoromethanesulfonate

C₂₇H₃₄AuClI₂N₂