Technology Process of C46H38N4
There total 11 articles about C46H38N4 which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
potassium carbonate;
tetrakis(triphenylphosphine) palladium(0);
In
ethanol; toluene;
at 120 ℃;
for 5h;
- Guidance literature:
-
Multi-step reaction with 8 steps
1.1: sodium t-butanolate; tri-tert-butyl phosphine / palladium diacetate / toluene / 12 h / 120 °C
2.1: N-Bromosuccinimide / N,N-dimethyl-formamide / 6 h / 0 °C
3.1: caesium carbonate; tri-tert-butyl phosphine / palladium diacetate / toluene / 12 h / 100 °C
4.1: tetrahydrofuran / 4 h / 60 °C
5.1: phosphoric acid / 12 h / 20 °C
6.1: potassium carbonate; copper; 18-crown-6 ether / 1,2-dichloro-benzene / 12 h / 180 °C
7.1: n-butyllithium / tetrahydrofuran / 1 h / -78 °C
7.2: 12 h
8.1: potassium carbonate / tetrakis(triphenylphosphine) palladium(0) / toluene; ethanol / 5 h / 120 °C
With
N-Bromosuccinimide; n-butyllithium; 18-crown-6 ether; tri-tert-butyl phosphine; phosphoric acid; copper; potassium carbonate; caesium carbonate; sodium t-butanolate;
tetrakis(triphenylphosphine) palladium(0); palladium diacetate;
In
tetrahydrofuran; ethanol; N,N-dimethyl-formamide; 1,2-dichloro-benzene; toluene;
- Guidance literature:
-
Multi-step reaction with 9 steps
1.1: phosphoric acid / 12 h / 20 °C
2.1: sodium t-butanolate; tri-tert-butyl phosphine / palladium diacetate / toluene / 12 h / 120 °C
3.1: N-Bromosuccinimide / N,N-dimethyl-formamide / 6 h / 0 °C
4.1: caesium carbonate; tri-tert-butyl phosphine / palladium diacetate / toluene / 12 h / 100 °C
5.1: tetrahydrofuran / 4 h / 60 °C
6.1: phosphoric acid / 12 h / 20 °C
7.1: potassium carbonate; copper; 18-crown-6 ether / 1,2-dichloro-benzene / 12 h / 180 °C
8.1: n-butyllithium / tetrahydrofuran / 1 h / -78 °C
8.2: 12 h
9.1: potassium carbonate / tetrakis(triphenylphosphine) palladium(0) / toluene; ethanol / 5 h / 120 °C
With
N-Bromosuccinimide; n-butyllithium; 18-crown-6 ether; tri-tert-butyl phosphine; phosphoric acid; copper; potassium carbonate; caesium carbonate; sodium t-butanolate;
tetrakis(triphenylphosphine) palladium(0); palladium diacetate;
In
tetrahydrofuran; ethanol; N,N-dimethyl-formamide; 1,2-dichloro-benzene; toluene;