Cirramycin A1, 12,13-deepoxy-12,13-didehydro-

Base Information

Chemical Name:Cirramycin A1, 12,13-deepoxy-12,13-didehydro-
CAS No.:50507-46-5
Molecular Formula:C31H51NO9
Molecular Weight:581.7379
Hs Code.:
DSSTox Substance ID:DTXSID801251745
Mol file:50507-46-5.mol

Synonyms:DTXSID801251745;Cirramycin A1, 12,13-deepoxy-12,13-didehydro-

Suppliers and Price of Cirramycin A1, 12,13-deepoxy-12,13-didehydro-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of Cirramycin A1, 12,13-deepoxy-12,13-didehydro-

Chemical Property:

Vapor Pressure:1.01E-26mmHg at 25°C
Boiling Point:760.9°Cat760mmHg
Flash Point:414°C
Density:1.16g/cm³
XLogP3:2.2
Hydrogen Bond Donor Count:3
Hydrogen Bond Acceptor Count:10
Rotatable Bond Count:6
Exact Mass:581.35638220
Heavy Atom Count:41
Complexity:935

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CCC1C(C=C(C=CC(=O)C(CC(C(C(C(CC(=O)O1)O)C)OC2C(C(C(C(O2)C)O)N(C)C)O)CC=O)C)C)C
Isomeric SMILES:CCC1C(/C=C(/C=C\C(=O)C(CC(C(C(C(CC(=O)O1)O)C)OC2C(C(C(C(O2)C)O)N(C)C)O)CC=O)C)\C)C

Technology Process of Cirramycin A1, 12,13-deepoxy-12,13-didehydro-

There total 5 articles about Cirramycin A1, 12,13-deepoxy-12,13-didehydro- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 80240-86-4
23-deoxy-23-iodo-5-O-mycaminosyltylonolide

: 50507-46-5
deepoxycirramycin A1

Guidance literature:: With sodium cyanoborohydride; In N,N,N,N,N,N-hexamethylphosphoric triamide; at 50 ℃; for 24h;
DOI:10.1248/cpb.30.97

Reference yield:

: 1401-69-0
15-[[(6-deoxy-2,6-di-O-methyl-β-D-allopyranosyl)-oxy]methyl]-6-[[3,6-dideoxy-4-O-(2,6-dideoxy-3-C-methyl-α-L-ribo-hexapyranosyl)-3-(dimethylamino)-β-D-glucopyranosyl]oxy]-16-ethyl-4-hydroxy-5,9,13-trimethyl-2,10-oxo-oxocyclo-hexadeca-11,13-diene-7...

: 50507-46-5
deepoxycirramycin A1

Guidance literature:: Multi-step reaction with 4 steps

1: 0.2N HCl / 4 h

2: 6.5 g / 0.5N HCl / 20 h / 90 °C

3: 1.4 g / I₂, triphenylphosphine / dimethylformamide / 25 h / Ambient temperature

4: 470 mg / NaBH₃CN / hexamethylphosphoric acid triamide / 24 h / 50 °C

With hydrogenchloride; iodine; sodium cyanoborohydride; triphenylphosphine; In N,N,N,N,N,N-hexamethylphosphoric triamide; N,N-dimethyl-formamide;
DOI:10.1248/cpb.30.97

Reference yield:

: 11032-98-7
demycarosyltylosin

: 50507-46-5
deepoxycirramycin A1

Guidance literature:: Multi-step reaction with 3 steps

1: 6.5 g / 0.5N HCl / 20 h / 90 °C

2: 1.4 g / I₂, triphenylphosphine / dimethylformamide / 25 h / Ambient temperature

3: 470 mg / NaBH₃CN / hexamethylphosphoric acid triamide / 24 h / 50 °C

With hydrogenchloride; iodine; sodium cyanoborohydride; triphenylphosphine; In N,N,N,N,N,N-hexamethylphosphoric triamide; N,N-dimethyl-formamide;
DOI:10.1248/cpb.30.97