(hydrotris(3,5-dimethylpyrazolyl)borate)Rh(neopentyl isocyanide)(η2-N-phenyl-N'-neopentyl-carbodiimide)

Base Information

Chemical Name:(hydrotris(3,5-dimethylpyrazolyl)borate)Rh(neopentyl isocyanide)(η2-N-phenyl-N'-neopentyl-carbodiimide)
CAS No.:139167-87-6
Molecular Formula:C₃₃H₄₉BN₉Rh
Molecular Weight:685.529
Hs Code.:

Synonyms:(hydrotris(3,5-dimethylpyrazolyl)borate)Rh(neopentyl isocyanide)(η2-N-phenyl-N'-neopentyl-carbodiimide)

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Chemical Property of (hydrotris(3,5-dimethylpyrazolyl)borate)Rh(neopentyl isocyanide)(η2-N-phenyl-N'-neopentyl-carbodiimide)

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Technology Process of (hydrotris(3,5-dimethylpyrazolyl)borate)Rh(neopentyl isocyanide)(η2-N-phenyl-N'-neopentyl-carbodiimide)

There total 1 articles about (hydrotris(3,5-dimethylpyrazolyl)borate)Rh(neopentyl isocyanide)(η2-N-phenyl-N'-neopentyl-carbodiimide) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

: (η2-hydrotris(3,5-dimethylpyrazol-1-yl)borate)bis(neopentylisocyanide) rhodium(I) complex

: 622-37-7
Phenyl azide

: 139167-87-6
(hydrotris(3,5-dimethylpyrazolyl)borate)Rh(neopentyl isocyanide)(η2-N-phenyl-N'-neopentyl-carbodiimide)

Guidance literature:: In tetrahydrofuran; hexane; byproducts: N2; under N2, addn of azide to soln. of complex (in hexane/THF 3:1); filtration, cooling (-20°C), filtration, redissolved in THF/hexane, cooling to -20°C, filtration, drying, elem. anal.;

Reference yield: 66.0%

: 139167-87-6
(hydrotris(3,5-dimethylpyrazolyl)borate)Rh(neopentyl isocyanide)(η2-N-phenyl-N'-neopentyl-carbodiimide)

: 72443-18-6
neopentylisonitrile

: 139167-94-5
(hydrotris(3,5-dimethylpyrazolyl)borate)Rh{C(N-neopentyl)N(Ph)C(N-neopentyl)}(CN-neopentyl)

Guidance literature:: In tetrahydrofuran; under N2, stirring soln. of the complex, addn. of isocyanide, stirring for 72 h,; reducing volume, standing for 1 month at -20°C, crystn., elem. anal.;

Reference yield: 58.0%

: 139167-87-6
(hydrotris(3,5-dimethylpyrazolyl)borate)Rh(neopentyl isocyanide)(η2-N-phenyl-N'-neopentyl-carbodiimide)

: (tris-3,5-dimethyl-pyrazolylborate)Rh(neopentyl isocyanide)(phenyl)H

Guidance literature:: With benzene; In benzene; byproducts: PhNCNCH2C(CH3)3; Irradiation (UV/VIS); under N2, soln. stirring, irradiation with λ>345 nm for 72 h; solv. removed, triturated with hexane, drying;