(4-(benzyloxy)phenyl)((1R,2R)-2-(2,5-bis(benzyloxy)phenyl)cyclopentyl)methanone

Base Information

Chemical Name:(4-(benzyloxy)phenyl)((1R,2R)-2-(2,5-bis(benzyloxy)phenyl)cyclopentyl)methanone
CAS No.:1357444-52-0
Molecular Formula:C₃₉H₃₆O₄
Molecular Weight:568.712
Hs Code.:

Synonyms:(4-(benzyloxy)phenyl)((1R,2R)-2-(2,5-bis(benzyloxy)phenyl)cyclopentyl)methanone

Suppliers and Price of (4-(benzyloxy)phenyl)((1R,2R)-2-(2,5-bis(benzyloxy)phenyl)cyclopentyl)methanone

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (4-(benzyloxy)phenyl)((1R,2R)-2-(2,5-bis(benzyloxy)phenyl)cyclopentyl)methanone

Chemical Property:

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Technology Process of (4-(benzyloxy)phenyl)((1R,2R)-2-(2,5-bis(benzyloxy)phenyl)cyclopentyl)methanone

There total 10 articles about (4-(benzyloxy)phenyl)((1R,2R)-2-(2,5-bis(benzyloxy)phenyl)cyclopentyl)methanone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1357444-50-8
(4-(benzyloxy)phenyl)(2-(2,5-bis(benzyloxy)phenyl)cyclopent-1-en-1-yl)methanone

: 1357444-51-9
(4-(benzyloxy)phenyl)((1S,2R)-2-(2,5-bis(benzyloxy)phenyl)cyclopentyl)methanone

: 1357444-52-0
(4-(benzyloxy)phenyl)((1R,2R)-2-(2,5-bis(benzyloxy)phenyl)cyclopentyl)methanone

Guidance literature:: With bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate; C₃₄H₄₄FeP₂; hydrogen; scandium tris(trifluoromethanesulfonate); In methanol; ethyl acetate; at 70 ℃; for 18h; under 51716.2 Torr; optical yield given as %ee; enantioselective reaction;
DOI:10.1021/ol203264a

Reference yield:

: 1357444-51-9
(4-(benzyloxy)phenyl)((1S,2R)-2-(2,5-bis(benzyloxy)phenyl)cyclopentyl)methanone

: 1357444-52-0
(4-(benzyloxy)phenyl)((1R,2R)-2-(2,5-bis(benzyloxy)phenyl)cyclopentyl)methanone

Guidance literature:: With hydrogenchloride; In 1,4-dioxane; at 20 ℃; for 0.75h;
DOI:10.1021/ol203264a

Reference yield:

: 123-31-9,8027-02-9
hydroquinone

: 1357444-52-0
(4-(benzyloxy)phenyl)((1R,2R)-2-(2,5-bis(benzyloxy)phenyl)cyclopentyl)methanone

Guidance literature:: Multi-step reaction with 6 steps

1.1: methanesulfonic acid / 72 h / 30 °C

2.1: potassium carbonate; sodium iodide / acetone / 18 h / Reflux; Inert atmosphere

3.1: water; sodium hydroxide / acetone / 5 h / 65 °C / Inert atmosphere

3.2: 8 h / 50 °C / Inert atmosphere

4.1: 4-methyl-morpholine / toluene / 16 h / 25 °C / Inert atmosphere

5.1: tetrahydrofuran; toluene / 4 h / 0 °C / Inert atmosphere

6.1: bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate; C₃₄H₄₄FeP₂; hydrogen; scandium tris(trifluoromethanesulfonate) / methanol; ethyl acetate / 18 h / 70 °C / 51716.2 Torr

With 4-methyl-morpholine; bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate; methanesulfonic acid; C₃₄H₄₄FeP₂; water; hydrogen; potassium carbonate; sodium iodide; sodium hydroxide; scandium tris(trifluoromethanesulfonate); In tetrahydrofuran; methanol; ethyl acetate; acetone; toluene;
DOI:10.1021/ol203264a