ethyl 2,3,6-tri-O-benzyl-4-O-(2,3-di-O-benzyl-β-D-glucopyranosyl)-1-thio-β-D-glucopyranoside

Base Information

Chemical Name:ethyl 2,3,6-tri-O-benzyl-4-O-(2,3-di-O-benzyl-β-D-glucopyranosyl)-1-thio-β-D-glucopyranoside
CAS No.:152964-73-3
Molecular Formula:C₄₉H₅₆O₁₀S
Molecular Weight:837.044
Hs Code.:

Synonyms:ethyl 2,3,6-tri-O-benzyl-4-O-(2,3-di-O-benzyl-β-D-glucopyranosyl)-1-thio-β-D-glucopyranoside

Suppliers and Price of ethyl 2,3,6-tri-O-benzyl-4-O-(2,3-di-O-benzyl-β-D-glucopyranosyl)-1-thio-β-D-glucopyranoside

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of ethyl 2,3,6-tri-O-benzyl-4-O-(2,3-di-O-benzyl-β-D-glucopyranosyl)-1-thio-β-D-glucopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of ethyl 2,3,6-tri-O-benzyl-4-O-(2,3-di-O-benzyl-β-D-glucopyranosyl)-1-thio-β-D-glucopyranoside

There total 10 articles about ethyl 2,3,6-tri-O-benzyl-4-O-(2,3-di-O-benzyl-β-D-glucopyranosyl)-1-thio-β-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

: ethyl 2,3,6-tri-O-benzyl-4-O-(2,3-di-O-benzyl-4,6-O-benzylidene-β-D-glucopyranosyl)-1-thio-β-D-glucopyranoside

: 152964-73-3
ethyl 2,3,6-tri-O-benzyl-4-O-(2,3-di-O-benzyl-β-D-glucopyranosyl)-1-thio-β-D-glucopyranoside

Guidance literature:: With acetic acid; at 100 ℃; for 1h;

Reference yield:

: 20701-61-5,56119-28-9,131564-36-8,142924-31-0,151123-92-1,141899-53-8
ethyl 4,6-O-benzylidene-1-thio-β-D-glucopyranoside

: 152964-73-3
ethyl 2,3,6-tri-O-benzyl-4-O-(2,3-di-O-benzyl-β-D-glucopyranosyl)-1-thio-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 6 steps

1: 1.) NaH / 1.) DMF, RT, 1 h, 2.) DMF, RT, 4 h

2: 72 percent / NaBH₃CN, mol. sieve 3A, HCl gas / tetrahydrofuran; diethyl ether / 0.17 h / Ambient temperature

3: 90 percent / 1.) mol. sieve 4A, 2.) silver triflate, sym-collidine / CH₂Cl₂ / 5.5 h / -40 °C

4: 81 percent / MeONa / methanol / 16 h / Ambient temperature

5: 1.) NaH / 1.) DMF, RT, 2.) DMF, RT, 16 h

6: 73 percent / 80percent aq. AcOH / 1 h / 100 °C

With 2,4,6-trimethyl-pyridine; hydrogenchloride; 3 A molecular sieve; 4 A molecular sieve; sodium methylate; silver trifluoromethanesulfonate; sodium hydride; sodium cyanoborohydride; acetic acid; In tetrahydrofuran; methanol; diethyl ether; dichloromethane;

Reference yield:

: 100-39-0
benzyl bromide

: 152964-73-3
ethyl 2,3,6-tri-O-benzyl-4-O-(2,3-di-O-benzyl-β-D-glucopyranosyl)-1-thio-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 6 steps

1: 1.) NaH / 1.) DMF, RT, 1 h, 2.) DMF, RT, 4 h

2: 72 percent / NaBH₃CN, mol. sieve 3A, HCl gas / tetrahydrofuran; diethyl ether / 0.17 h / Ambient temperature

3: 90 percent / 1.) mol. sieve 4A, 2.) silver triflate, sym-collidine / CH₂Cl₂ / 5.5 h / -40 °C

4: 81 percent / MeONa / methanol / 16 h / Ambient temperature

5: 1.) NaH / 1.) DMF, RT, 2.) DMF, RT, 16 h

6: 73 percent / 80percent aq. AcOH / 1 h / 100 °C

With 2,4,6-trimethyl-pyridine; hydrogenchloride; 3 A molecular sieve; 4 A molecular sieve; sodium methylate; silver trifluoromethanesulfonate; sodium hydride; sodium cyanoborohydride; acetic acid; In tetrahydrofuran; methanol; diethyl ether; dichloromethane;