(2-L-1,2,4/3,5)-1-acetamido-5-fluoro-2,3,4-tri-O-benzyl-2,3,4-cyclohexanetriol

Base Information

Chemical Name:(2-L-1,2,4/3,5)-1-acetamido-5-fluoro-2,3,4-tri-O-benzyl-2,3,4-cyclohexanetriol
CAS No.:214134-43-7
Molecular Formula:C₂₉H₃₂FNO₄
Molecular Weight:477.576
Hs Code.:

Synonyms:(2-L-1,2,4/3,5)-1-acetamido-5-fluoro-2,3,4-tri-O-benzyl-2,3,4-cyclohexanetriol

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Chemical Property of (2-L-1,2,4/3,5)-1-acetamido-5-fluoro-2,3,4-tri-O-benzyl-2,3,4-cyclohexanetriol

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Technology Process of (2-L-1,2,4/3,5)-1-acetamido-5-fluoro-2,3,4-tri-O-benzyl-2,3,4-cyclohexanetriol

There total 6 articles about (2-L-1,2,4/3,5)-1-acetamido-5-fluoro-2,3,4-tri-O-benzyl-2,3,4-cyclohexanetriol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: 214134-41-5
(2-L-1,2,4,5/3)-1-acetamido-2,3,4-tri-O-benzyl-2,3,4,5-cyclohexanetetrol

: 214134-43-7
(2-L-1,2,4/3,5)-1-acetamido-5-fluoro-2,3,4-tri-O-benzyl-2,3,4-cyclohexanetriol

Guidance literature:: With 4,4'-diaminostilbene-2,2'-disulfonic acid; In dichloromethane; for 4h; Ambient temperature; 1.) 0 deg C;
DOI:10.1016/S0040-4039(98)01428-2

Reference yield:

: 87940-08-7
(2-L-1,2,4,5/3)-1-amino-2,3,4-tri-O-benzyl-2,3,4,5-cyclohexanetetrol

: 214134-43-7
(2-L-1,2,4/3,5)-1-acetamido-5-fluoro-2,3,4-tri-O-benzyl-2,3,4-cyclohexanetriol

Guidance literature:: Multi-step reaction with 2 steps

1: 90 percent / methanol / 4 h / 20 °C

2: 70 percent / DAST / CH₂Cl₂ / 6 h / 0 - 20 °C

With 4,4'-diaminostilbene-2,2'-disulfonic acid; In methanol; dichloromethane;
DOI:10.1081/CAR-120026471

Reference yield:

: 87940-06-5,87984-32-5
(2R,3S,4S,5S)-2,3,4-Tris-benzyloxy-5-hydroxy-cyclohexanone oxime

: 214134-43-7
(2-L-1,2,4/3,5)-1-acetamido-5-fluoro-2,3,4-tri-O-benzyl-2,3,4-cyclohexanetriol

Guidance literature:: Multi-step reaction with 4 steps

1: 91 percent / 1.) NaH / dimethylformamide / 24 h / 100 °C / 1.) 0 deg C

2: 8 percent / LiAlH₄ / tetrahydrofuran / 12 h / Heating

3: 90 percent / methanol / 8 h / Ambient temperature; 1.) 0 deg C

4: 70 percent / DAST / CH₂Cl₂ / 4 h / Ambient temperature; 1.) 0 deg C

With lithium aluminium tetrahydride; sodium hydride; 4,4'-diaminostilbene-2,2'-disulfonic acid; In tetrahydrofuran; methanol; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1016/S0040-4039(98)01428-2