(2-L-1,2,4,5/3)-1-amino-2,3,4-tri-O-benzyl-2,3,4,5-cyclohexanetetrol

Base Information

• Chemical Name: (2-L-1,2,4,5/3)-1-amino-2,3,4-tri-O-benzyl-2,3,4,5-cyclohexanetetrol
• CAS No.: 87940-08-7
• Molecular Formula: C₂₇H₃₁NO₄
• Molecular Weight: 433.547
• Mol file: 87940-08-7.mol

Synonyms:(2-L-1,2,4,5/3)-1-amino-2,3,4-tri-O-benzyl-2,3,4,5-cyclohexanetetrol

Chemical Property of (2-L-1,2,4,5/3)-1-amino-2,3,4-tri-O-benzyl-2,3,4,5-cyclohexanetetrol

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (2-L-1,2,4,5/3)-1-amino-2,3,4-tri-O-benzyl-2,3,4,5-cyclohexanetetrol

There total 12 articles about (2-L-1,2,4,5/3)-1-amino-2,3,4-tri-O-benzyl-2,3,4,5-cyclohexanetetrol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

(2-L-2,4,5/3)-1-benzyloxyimino-2,3,4-tri-O-benzyl-2,3,4,5-cyclohexanetetrol (651325-18-7) → (2-L-1,2,4,5/3)-1-amino-2,3,4-tri-O-benzyl-2,3,4,5-cyclohexanetetrol (87940-08-7) + (2-L-1,3/2,4,5)-1-amino-2,3,4-tri-O-benzyl-2,3,4,5-cyclohexanetetrol (87984-35-8) + (2-L-1,3/2,4,5)-1-(benzyloxy)amino-2,3,4-tri-O-benzyl-2,3,4,5-cyclohexanetetrol (214134-40-4)

Guidance literature:

With lithium aluminium tetrahydride; In tetrahydrofuran; for 12h; Heating;

DOI:10.1081/CAR-120026471

Reference yield: 16.0%

(2R,3S,4S,5S)-2,3,4-Tris-benzyloxy-5-hydroxy-cyclohexanone oxime (87940-06-5,87984-32-5) → (2-L-1,2,4,5/3)-1-amino-2,3,4-tri-O-benzyl-2,3,4,5-cyclohexanetetrol (87940-08-7) + (2-L-1,3/2,4,5)-1-amino-2,3,4-tri-O-benzyl-2,3,4,5-cyclohexanetetrol (87984-35-8)

Guidance literature:

With lithium aluminium tetrahydride; In tetrahydrofuran; for 6h; Heating;

DOI:10.1055/s-1983-30478

Reference yield: 8.0%

(2R,3S,4S,5S)-2,3,4-Tris-benzyloxy-5-hydroxy-cyclohexanone O-benzyl-oxime → (2-L-1,2,4,5/3)-1-amino-2,3,4-tri-O-benzyl-2,3,4,5-cyclohexanetetrol (87940-08-7) + (2-L-1,3/2,4,5)-1-amino-2,3,4-tri-O-benzyl-2,3,4,5-cyclohexanetetrol (87984-35-8) + (2-L-1,3/2,4,5)-1-(benzyloxy)amino-2,3,4-tri-O-benzyl-2,3,4,5-cyclohexanetetrol (214134-40-4)

Guidance literature:

With lithium aluminium tetrahydride; In tetrahydrofuran; for 12h; Heating;

DOI:10.1016/S0040-4039(98)01428-2

upstream raw materials:

(2R,3S,4S,5S)-2,3,4-Tris-benzyloxy-5-hydroxy-cyclohexanone oxime

(2-L-2,4,5/3)-1-benzyloxyimino-2,3,4-tri-O-benzyl-2,3,4,5-cyclohexanetetrol

methyl 6-deoxy-α-D-xylo-hex-5-enopyranoside

1L-(2,4,5/3)-2,3,4-Tri-O-benzyl-2,3,4,5-tetrahydroxy-1-cyclohexanon

Downstream raw materials:

(2-L-1,2,4,5/3)-1-acetamido-2,3,4-tri-O-benzyl-2,3,4,5-cyclohexanetetrol

(2-L-1,2,4/3,5)-1-acetamido-5-fluoro-2,3,4-tri-O-benzyl-2,3,4-cyclohexanetriol