tert-butyl 2-[[(4R,6R)-2,2-dimethyl-6-((E)-3-methylhexa-3,5-dienyl)1,3dioxan4-yl]ethoxy]diphenylsilane

Base Information

Chemical Name:tert-butyl 2-[[(4R,6R)-2,2-dimethyl-6-((E)-3-methylhexa-3,5-dienyl)1,3dioxan4-yl]ethoxy]diphenylsilane
CAS No.:1445989-96-7
Molecular Formula:C₃₁H₄₄O₃Si
Molecular Weight:492.774
Hs Code.:

Synonyms:tert-butyl 2-[[(4R,6R)-2,2-dimethyl-6-((E)-3-methylhexa-3,5-dienyl)1,3dioxan4-yl]ethoxy]diphenylsilane

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Chemical Property of tert-butyl 2-[[(4R,6R)-2,2-dimethyl-6-((E)-3-methylhexa-3,5-dienyl)1,3dioxan4-yl]ethoxy]diphenylsilane

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Technology Process of tert-butyl 2-[[(4R,6R)-2,2-dimethyl-6-((E)-3-methylhexa-3,5-dienyl)1,3dioxan4-yl]ethoxy]diphenylsilane

There total 4 articles about tert-butyl 2-[[(4R,6R)-2,2-dimethyl-6-((E)-3-methylhexa-3,5-dienyl)1,3dioxan4-yl]ethoxy]diphenylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

: 1445989-95-6
C₂₈H₄₀O₃Si

: 77-76-9
2,2-dimethoxy-propane

: 1445989-96-7
tert-butyl 2-[[(4R,6R)-2,2-dimethyl-6-((E)-3-methylhexa-3,5-dienyl)1,3dioxan4-yl]ethoxy]diphenylsilane

Guidance literature:: With camphor-10-sulfonic acid; In dichloromethane; at 0 - 20 ℃; for 2h; Inert atmosphere;
DOI:10.1021/jo400929m

Reference yield:

: 1445989-90-1
(3S,5R,E)-1-[(S)-4-benzyl-2-thioxothiazolidin-3-yl]-5-(tert-butyldimethylsilyloxy)-3-hydroxy-8-methylundeca-8,10-dien-1-one

: 1445989-96-7
tert-butyl 2-[[(4R,6R)-2,2-dimethyl-6-((E)-3-methylhexa-3,5-dienyl)1,3dioxan4-yl]ethoxy]diphenylsilane

Guidance literature:: Multi-step reaction with 4 steps

1: sodium tetrahydroborate / methanol / 0.25 h / 0 °C / Inert atmosphere

2: camphor-10-sulfonic acid / dichloromethane; methanol / 2 h / 0 - 20 °C / Inert atmosphere

3: triethylamine; dmap / dichloromethane / 2 h / 0 - 20 °C / Inert atmosphere

4: camphor-10-sulfonic acid / dichloromethane / 2 h / 0 - 20 °C / Inert atmosphere

With dmap; sodium tetrahydroborate; camphor-10-sulfonic acid; triethylamine; In methanol; dichloromethane;
DOI:10.1021/jo400929m

Reference yield:

: 1445989-93-4
C₁₈H₃₆O₃Si

: 1445989-96-7
tert-butyl 2-[[(4R,6R)-2,2-dimethyl-6-((E)-3-methylhexa-3,5-dienyl)1,3dioxan4-yl]ethoxy]diphenylsilane

Guidance literature:: Multi-step reaction with 3 steps

1: camphor-10-sulfonic acid / dichloromethane; methanol / 2 h / 0 - 20 °C / Inert atmosphere

2: triethylamine; dmap / dichloromethane / 2 h / 0 - 20 °C / Inert atmosphere

3: camphor-10-sulfonic acid / dichloromethane / 2 h / 0 - 20 °C / Inert atmosphere

With dmap; camphor-10-sulfonic acid; triethylamine; In methanol; dichloromethane;
DOI:10.1021/jo400929m