methyl 6-allyl-5-oxo-7-(3,4,5-trimethoxyphenyl)-6,7-dihydro-5H-indeno[5,6-d][1,3]dioxole-6-carboxylate

Base Information

Chemical Name:methyl 6-allyl-5-oxo-7-(3,4,5-trimethoxyphenyl)-6,7-dihydro-5H-indeno[5,6-d][1,3]dioxole-6-carboxylate
CAS No.:132155-41-0
Molecular Formula:C₂₄H₂₄O₈
Molecular Weight:440.45
Hs Code.:

Synonyms:methyl 6-allyl-5-oxo-7-(3,4,5-trimethoxyphenyl)-6,7-dihydro-5H-indeno[5,6-d][1,3]dioxole-6-carboxylate

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Chemical Property of methyl 6-allyl-5-oxo-7-(3,4,5-trimethoxyphenyl)-6,7-dihydro-5H-indeno[5,6-d][1,3]dioxole-6-carboxylate

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Technology Process of methyl 6-allyl-5-oxo-7-(3,4,5-trimethoxyphenyl)-6,7-dihydro-5H-indeno[5,6-d][1,3]dioxole-6-carboxylate

There total 2 articles about methyl 6-allyl-5-oxo-7-(3,4,5-trimethoxyphenyl)-6,7-dihydro-5H-indeno[5,6-d][1,3]dioxole-6-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 556-56-9
allyl iodid

: methyl 5-oxo-7-(3,4,5-trimethoxyphenyl)-5H-indeno[5,6-d][1,3]dioxole-6-carboxylate

: 132155-41-0
methyl 6-allyl-5-oxo-7-(3,4,5-trimethoxyphenyl)-6,7-dihydro-5H-indeno[5,6-d][1,3]dioxole-6-carboxylate

Guidance literature:: methyl 5-oxo-7-(3,4,5-trimethoxyphenyl)-5H-indeno[5,6-d][1,3]dioxole-6-carboxylate; With diiodo(p-cymene)ruthenium(II) dimer; hydrogen; toluene-4-sulfonic acid; In 1,3,5-trimethyl-benzene; at 50 ℃; for 24h; under 41372.9 Torr; Autoclave;

allyl iodid; With 18-crown-6 ether; sodium carbonate; In tetrahydrofuran; 1,3,5-trimethyl-benzene; at 20 ℃; for 24h;
DOI:10.1021/acs.orglett.1c02568

Reference yield:

: 94671-08-6,132127-74-3
(6R,7S)-5-Oxo-7-(3,4,5-trimethoxy-phenyl)-6,7-dihydro-5H-indeno[5,6-d][1,3]dioxole-6-carboxylic acid methyl ester

: 106-95-6
allyl bromide

: 132155-41-0
methyl 6-allyl-5-oxo-7-(3,4,5-trimethoxyphenyl)-6,7-dihydro-5H-indeno[5,6-d][1,3]dioxole-6-carboxylate

Guidance literature:: With sodium hexamethyldisilazane; Yield given. Multistep reaction; 1.) DMF, RT, 15 min, 2.) a) 50 deg C, 1 h, b) 40 deg C, 16 h;
DOI:10.1021/jm00107a016

Reference yield:

: 132155-41-0
methyl 6-allyl-5-oxo-7-(3,4,5-trimethoxyphenyl)-6,7-dihydro-5H-indeno[5,6-d][1,3]dioxole-6-carboxylate

: 132127-72-1,132201-46-8
C₂₁H₂₀O₈

Guidance literature:: Multi-step reaction with 6 steps

1: 3.2 g / NaBH₄ / methanol; H₂O / 1.25 h / Ambient temperature

2: 1.) OsO₄, 2.) NaIO₄ / 1.) H₂O, THF, RT, 20 min, 2.) 1 h

3: NaBH₄ / methanol; H₂O / 1 h / Ambient temperature

4: 320 mg / MnO₂ / CH₂Cl₂ / 1 h / Ambient temperature

5: trimethylsilyl iodide (TMSI) / CH₂Cl₂ / 7 h / Ambient temperature

6: 85 percent / NaBH₄ / methanol; H₂O / 1.5 h / Ambient temperature

With manganese(IV) oxide; sodium tetrahydroborate; sodium periodate; osmium(VIII) oxide; trimethylsilyl iodide; In methanol; dichloromethane; water;
DOI:10.1021/jm00107a016