(1Z,5E)-1-(ethoxycarbonyl)-6,10-dimethylundeca-1,5,9-trien-2-yl diethyl phosphate

Base Information

Chemical Name:(1Z,5E)-1-(ethoxycarbonyl)-6,10-dimethylundeca-1,5,9-trien-2-yl diethyl phosphate
CAS No.:157327-72-5
Molecular Formula:C₂₀H₃₅O₆P
Molecular Weight:402.468
Hs Code.:

Synonyms:(1Z,5E)-1-(ethoxycarbonyl)-6,10-dimethylundeca-1,5,9-trien-2-yl diethyl phosphate

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Chemical Property of (1Z,5E)-1-(ethoxycarbonyl)-6,10-dimethylundeca-1,5,9-trien-2-yl diethyl phosphate

Chemical Property:

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Technology Process of (1Z,5E)-1-(ethoxycarbonyl)-6,10-dimethylundeca-1,5,9-trien-2-yl diethyl phosphate

There total 1 articles about (1Z,5E)-1-(ethoxycarbonyl)-6,10-dimethylundeca-1,5,9-trien-2-yl diethyl phosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 5389-87-7
1-chloro-3,7-dimethylocta-2,6-diene

: 157327-72-5
(1Z,5E)-1-(ethoxycarbonyl)-6,10-dimethylundeca-1,5,9-trien-2-yl diethyl phosphate

Guidance literature:: Multi-step reaction with 2 steps

1: 51 percent / NaH; n-BuLi / tetrahydrofuran; hexane / 0.5 h / 0 - 20 °C

2: 79 percent / LiHMDS / tetrahydrofuran; diethyl ether / 3.5 h / 20 °C

With n-butyllithium; sodium hydride; lithium hexamethyldisilazane; In tetrahydrofuran; diethyl ether; hexane;
DOI:10.1021/jo026295b

Reference yield:

: 157327-72-5
(1Z,5E)-1-(ethoxycarbonyl)-6,10-dimethylundeca-1,5,9-trien-2-yl diethyl phosphate

: 477960-36-4
pentafluorophenyl (2E,6E)-3,7,11-trimethyl-2,6,10-dodecatrienoate

Guidance literature:: Multi-step reaction with 3 steps

1: 93 percent / CuI; MeLi / tetrahydrofuran; diethyl ether / 3 h / -30 °C

2: 78 percent / aq. NaOH; NaHCO₃ / tetrahydrofuran

3: 99 percent / DCC / ethyl acetate / 24 h

With sodium hydroxide; copper(l) iodide; methyllithium; sodium hydrogencarbonate; dicyclohexyl-carbodiimide; In tetrahydrofuran; diethyl ether; ethyl acetate;
DOI:10.1021/jo026295b

Reference yield:

: 157327-72-5
(1Z,5E)-1-(ethoxycarbonyl)-6,10-dimethylundeca-1,5,9-trien-2-yl diethyl phosphate

: (2E,6E)-3-((2)H3)methyl-7,11-dimethylundeca-2,6,10-trienyl diphosphate trisammonium salt

Guidance literature:: Multi-step reaction with 3 steps

1.1: copper(l) iodide / diethyl ether / 0 - 5 °C

1.2: 1.5 h / -78 °C

2.1: lithium aluminium tetrahydride / diethyl ether / 0.5 h / 0 °C

3.1: methanesulfonyl chloride; lithium bromide / tetrahydrofuran / -45 - 0 °C

3.3: Dowex 50W (NH₄+ form) cation exchange resin

With copper(l) iodide; lithium aluminium tetrahydride; methanesulfonyl chloride; lithium bromide; In tetrahydrofuran; diethyl ether;
DOI:10.1021/ja211820p