(β-octaks(bromo)-meso-tri(phenyl)corrole)copper

Base Information

• Chemical Name: (β-octaks(bromo)-meso-tri(phenyl)corrole)copper
• CAS No.: 444987-87-5
• Molecular Formula: C₃₇H₁₅Br₈CuN₄
• Molecular Weight: 1218.33
• Mol file: 444987-87-5.mol

Synonyms:(β-octaks(bromo)-meso-tri(phenyl)corrole)copper

Chemical Property of (β-octaks(bromo)-meso-tri(phenyl)corrole)copper

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (β-octaks(bromo)-meso-tri(phenyl)corrole)copper

There total 4 articles about (β-octaks(bromo)-meso-tri(phenyl)corrole)copper which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 51.0%

copper(II) meso-triphenylcorrolate(2-) (444987-83-1) → (2,3,7,8,12,13,17,18-octabromo-5,10,15-triphenylcorrolato)copper (444987-87-5)

Guidance literature:

copper(II) meso-triphenylcorrolate^(2-); With bromine; In chloroform; at 20 ℃; for 1h;

With pyridine; In chloroform; for 1h;

DOI:10.1016/j.jinorgbio.2015.07.017

Reference yield:

5,10,15-tris(phenyl)corrole → (2,3,7,8,12,13,17,18-octabromo-5,10,15-triphenylcorrolato)copper (444987-87-5)

Guidance literature:

Multi-step reaction with 2 steps

1: pyridine

2: sodium metabisulfite / water; chloroform; pyridine

With sodium metabisulfite; In pyridine; chloroform; water;

DOI:10.1021/ja0113697

Reference yield:

copper(II) meso-triphenylcorrolate(2-) (444987-83-1) + bromine (7726-95-6) → (2,3,7,8,12,13,17,18-octabromo-5,10,15-triphenylcorrolato)copper (444987-87-5)

Guidance literature:

With sodium metabisulfite; In pyridine; chloroform; water; to stirred soln. of Cu(III)-complex in CHCl3 added Br2 dissolved in CHCl3 over 15 min at room temp.; mixt. stirred for 1 h; pyridine dissolved in CHCl3 added dropwise over 15 min; soln. stirred for 1 h; aq. soln. of sodium metabisulfite added; org. layer sepd.; dried (anhyd. Na2SO4); solvent evapd.; purified by chromy. on silica gel (hexane/CH2Cl2 as eluent);

DOI:10.1021/ja0113697

upstream raw materials:

copper(II) meso-triphenylcorrolate^(2-)

bromine

(meso-tri(phenyl)corrole)copper

Downstream raw materials:

copper 2,3,7,8,12,13,17,18-octakis[4-(trifluoromethyl)-phenyl]-5,10,15-triphenylcorrole

copper 2,3,5,7,8,10,12,13,15,17,18-undecaphenylcorrole

copper 2,3,7,8,12,13,17,18-octakis(4-methylphenyl)-5,10,15-triphenylcorrole

C₆₉H₄₇CuN₄O₁₆