Ethyl phenyl selenone

Base Information

• Chemical Name: Ethyl phenyl selenone
• CAS No.: 98750-94-8
• Molecular Formula: C8H10O2Se
• Molecular Weight: 217.1238
• Hs Code.: 2902909090
• Mol file: 98750-94-8.mol

Synonyms:Ethaneselenonyl-benzene;Benzene,(ethylselenonyl);Ethyl phenyl selenone;(ethylselenonyl)benzene;Benzene,(ethylselenoyl);

Chemical Property of Ethyl phenyl selenone

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 34.14000
• Density: g/cm³
• LogP: 1.21670

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Ethyl phenyl selenone

There total 2 articles about Ethyl phenyl selenone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

ethyl phenyl selenide (17774-38-8) → ethyl phenyl selenone (98750-94-8)

Guidance literature:

With potassium permanganate; In dichloromethane; at 20 ℃; for 0.5h;

DOI:10.1039/c39850000569

Reference yield:

diphenyl diselenide (1666-13-3) → ethyl phenyl selenone (98750-94-8)

Guidance literature:

Multi-step reaction with 2 steps

1.1: sodium tetrahydroborate / ethanol / 0.5 h / 0 °C / Inert atmosphere

1.2: 22 h / Inert atmosphere

2.1: potassium carbonate; 3-chloro-benzenecarboperoxoic acid / dichloromethane; water / 2 h / 20 °C

With sodium tetrahydroborate; potassium carbonate; 3-chloro-benzenecarboperoxoic acid; In ethanol; dichloromethane; water;

DOI:10.1021/acs.orglett.9b03375

Reference yield:

4-Nitrobenzylpyridin (1083-48-3) + ethyl phenyl selenone (98750-94-8) → C14H15N2O2(1+)*C6H5O2Se(1-)

Guidance literature:

In water; acetone; at 37 ℃; Rate constant; Product distribution; other phenyl selenones; Tris-HCl buffer, pH 7.4;

DOI:10.1021/jm00168a003

upstream raw materials:

ethyl phenyl selenide

diphenyl diselenide

Refernces

• 1、 Krief, Alain,Dumont, Willy,Denis, Jean-Noel,Evrard, Guy,Norberg, Bernadette. "Synthesis of Selenones: A Comparative Study". . p. 569 - 570. Retrieved 2007/10/02.