2-[(E)-(7S,8S)-7-Allyloxy-8-hydroxy-9-(4-methoxy-benzyloxy)-non-1-enyl]-6-methoxy-benzoic acid methyl ester

Base Information

Chemical Name:2-[(E)-(7S,8S)-7-Allyloxy-8-hydroxy-9-(4-methoxy-benzyloxy)-non-1-enyl]-6-methoxy-benzoic acid methyl ester
CAS No.:366800-17-1
Molecular Formula:C₂₉H₃₈O₇
Molecular Weight:498.617
Hs Code.:

Synonyms:2-[(E)-(7S,8S)-7-Allyloxy-8-hydroxy-9-(4-methoxy-benzyloxy)-non-1-enyl]-6-methoxy-benzoic acid methyl ester

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Chemical Property of 2-[(E)-(7S,8S)-7-Allyloxy-8-hydroxy-9-(4-methoxy-benzyloxy)-non-1-enyl]-6-methoxy-benzoic acid methyl ester

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Technology Process of 2-[(E)-(7S,8S)-7-Allyloxy-8-hydroxy-9-(4-methoxy-benzyloxy)-non-1-enyl]-6-methoxy-benzoic acid methyl ester

There total 10 articles about 2-[(E)-(7S,8S)-7-Allyloxy-8-hydroxy-9-(4-methoxy-benzyloxy)-non-1-enyl]-6-methoxy-benzoic acid methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 79439-15-9
methyl trans-2-nonen-8-ynoate

: 366800-17-1
2-[(E)-(7S,8S)-7-Allyloxy-8-hydroxy-9-(4-methoxy-benzyloxy)-non-1-enyl]-6-methoxy-benzoic acid methyl ester

Guidance literature:: Multi-step reaction with 7 steps

1.1: 99 percent / DIBAH / CH₂Cl₂ / 16 h / 23 °C

2.1: 78 percent / NaH / dimethylformamide

3.1: 72 percent / MeSO2NH2; aq. K2CO3; K3Fe(CN)6 / K2OsO2(OH)4; AD-mix α / 2-methyl-propan-2-ol

4.1: 94 percent / p-TsOH / tetrahydrofuran / 16 h / 23 °C

5.1: Bu₃SnH; AIBN / toluene / 5 h / 100 °C

5.2: LiCl; 2,6-di-tert-butyl-4-methylphenol / Pd(PPh₃)2Cl₂ / dimethylformamide / 18 h / 100 °C

6.1: 90 percent / aq. AcOH / 18 h / 23 °C

7.1: nBu₂SnO / toluene / 6 h / 120 °C

7.2: CsF / dimethylformamide / 18 h / 23 °C

With 2,2'-azobis(isobutyronitrile); methanesulfonamide; tri-n-butyl-tin hydride; sodium hydride; diisobutylaluminium hydride; di(n-butyl)tin oxide; potassium carbonate; toluene-4-sulfonic acid; acetic acid; potassium hexacyanoferrate(III); AD-mix-α; potassium dioxotetrahydroxoosmate(VI); In tetrahydrofuran; dichloromethane; N,N-dimethyl-formamide; toluene; tert-butyl alcohol; 3.1: Sharpless asymmetric dihydroxylation / 5.2: Stile cross-coupling reaction;
DOI:10.1055/s-2001-16056

Reference yield:

: 173043-70-4
(E)-2-nonen-8-yn-1-ol

: 366800-17-1
2-[(E)-(7S,8S)-7-Allyloxy-8-hydroxy-9-(4-methoxy-benzyloxy)-non-1-enyl]-6-methoxy-benzoic acid methyl ester

Guidance literature:: Multi-step reaction with 6 steps

1.1: 78 percent / NaH / dimethylformamide

2.1: 72 percent / MeSO2NH2; aq. K2CO3; K3Fe(CN)6 / K2OsO2(OH)4; AD-mix α / 2-methyl-propan-2-ol

3.1: 94 percent / p-TsOH / tetrahydrofuran / 16 h / 23 °C

4.1: Bu₃SnH; AIBN / toluene / 5 h / 100 °C

4.2: LiCl; 2,6-di-tert-butyl-4-methylphenol / Pd(PPh₃)2Cl₂ / dimethylformamide / 18 h / 100 °C

5.1: 90 percent / aq. AcOH / 18 h / 23 °C

6.1: nBu₂SnO / toluene / 6 h / 120 °C

6.2: CsF / dimethylformamide / 18 h / 23 °C

With 2,2'-azobis(isobutyronitrile); methanesulfonamide; tri-n-butyl-tin hydride; sodium hydride; di(n-butyl)tin oxide; potassium carbonate; toluene-4-sulfonic acid; acetic acid; potassium hexacyanoferrate(III); AD-mix-α; potassium dioxotetrahydroxoosmate(VI); In tetrahydrofuran; N,N-dimethyl-formamide; toluene; tert-butyl alcohol; 2.1: Sharpless asymmetric dihydroxylation / 4.2: Stile cross-coupling reaction;
DOI:10.1055/s-2001-16056

Reference yield:

: 366800-07-9
1-Methoxy-4-[((E)-non-2-en-8-ynyl)oxymethyl]-benzene

: 366800-17-1
2-[(E)-(7S,8S)-7-Allyloxy-8-hydroxy-9-(4-methoxy-benzyloxy)-non-1-enyl]-6-methoxy-benzoic acid methyl ester

Guidance literature:: Multi-step reaction with 5 steps

1.1: 72 percent / MeSO2NH2; aq. K2CO3; K3Fe(CN)6 / K2OsO2(OH)4; AD-mix α / 2-methyl-propan-2-ol

2.1: 94 percent / p-TsOH / tetrahydrofuran / 16 h / 23 °C

3.1: Bu₃SnH; AIBN / toluene / 5 h / 100 °C

3.2: LiCl; 2,6-di-tert-butyl-4-methylphenol / Pd(PPh₃)2Cl₂ / dimethylformamide / 18 h / 100 °C

4.1: 90 percent / aq. AcOH / 18 h / 23 °C

5.1: nBu₂SnO / toluene / 6 h / 120 °C

5.2: CsF / dimethylformamide / 18 h / 23 °C

With 2,2'-azobis(isobutyronitrile); methanesulfonamide; tri-n-butyl-tin hydride; di(n-butyl)tin oxide; potassium carbonate; toluene-4-sulfonic acid; acetic acid; potassium hexacyanoferrate(III); AD-mix-α; potassium dioxotetrahydroxoosmate(VI); In tetrahydrofuran; toluene; tert-butyl alcohol; 1.1: Sharpless asymmetric dihydroxylation / 3.2: Stile cross-coupling reaction;
DOI:10.1055/s-2001-16056