.beta.-D-Glucopyranuronic acid, 5-C-bromo-, methyl ester, tetraacetate

Base Information

Chemical Name:.beta.-D-Glucopyranuronic acid, 5-C-bromo-, methyl ester, tetraacetate
CAS No.:65615-69-2
Molecular Formula:C₁₅H₁₉BrO₁₁
Molecular Weight:455.213
Hs Code.:

Synonyms:methyl (5R)-1,2,3,4-tetra-O-acetyl-5-C-bromo-β-D-glucopyranuronate

Suppliers and Price of .beta.-D-Glucopyranuronic acid, 5-C-bromo-, methyl ester, tetraacetate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
5-Bromo-β-D-glucopyranuronicAcidMethylEsterTetraacetate
1g
$ 105.00

Total 3 raw suppliers

Chemical Property of .beta.-D-Glucopyranuronic acid, 5-C-bromo-, methyl ester, tetraacetate

Chemical Property:

Melting Point:>130°C (dec.)
Solubility.:Chloroform (Slightly), Ethyl Acetate (Slightly)

Purity/Quality:

99% ^*data from raw suppliers

5-Bromo-β-D-glucopyranuronicAcidMethylEsterTetraacetate ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Uses 5-Bromo-β-D-glucopyranuronic Acid Methyl Ester Tetraacetate is an intermediate in the synthesis of heparin building blocks.

Technology Process of .beta.-D-Glucopyranuronic acid, 5-C-bromo-, methyl ester, tetraacetate

There total 2 articles about .beta.-D-Glucopyranuronic acid, 5-C-bromo-, methyl ester, tetraacetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: 7355-18-2
(2S,3S,4S,5R,6S)-3,4,5,6-Tetraacetoxy-tetrahydro-pyran-2-carboxylic acid methyl ester

: 65615-69-2
methyl (5R)-1,2,3,4-tetra-O-acetyl-5-C-bromo-β-D-glucopyranuronate

Guidance literature:: With N-Bromosuccinimide; In tetrachloromethane; UV-irradiation; Reflux;
DOI:10.1039/c6ob00283h

Reference yield:

: 65615-69-2
methyl (5R)-1,2,3,4-tetra-O-acetyl-5-C-bromo-β-D-glucopyranuronate

Guidance literature:: entspr. Ester 4, N-Bromsuccinimid;

Reference yield: 63.5%

: 65615-69-2
methyl (5R)-1,2,3,4-tetra-O-acetyl-5-C-bromo-β-D-glucopyranuronate

: 108032-41-3
methyl 1,2,3,4-tetra-O-acetyl-α-L-idopyranuronate

: 7355-18-2
(2S,3S,4S,5R,6S)-3,4,5,6-Tetraacetoxy-tetrahydro-pyran-2-carboxylic acid methyl ester

Guidance literature:: With tri-n-butyl-tin hydride; In toluene; for 30h; Product distribution; Heating; variation of scale and reaction time; practical conversion of a D-glucuronic acid derivative into L-iduronic acid derivative by reductive epimerization (after a photobromination);
DOI:10.1016/S0008-6215(00)90357-4